SIOC English
有机化学
高级检索

有机化学 ›› 2011, Vol. 31 ›› Issue (9): 1337-1349.    下一篇

综述与进展

有机二阶非线性光学发色团的研究进展

李倩倩，秦金贵，李振*   

  1. (武汉大学化学与分子科学学院 湖北省有机高分子光电功能材料重点实验室 武汉 430072)
  • 收稿日期:2010-08-08 修回日期:2011-04-01 发布日期:2011-04-12
  • 通讯作者: 李振 E-mail:lizhen@whu.edu.cn

Recent Progress of Organic Second-Order Nonlinear Optical Chro-mophores

LI Qian-Qian, QIN Jin-Gui, LI Zhen   

  1. (Hubei Key Laboratory on Organic and Polymeric Opto-Electronic Materials, Department of Chemistry, Wuhan University, Wuhan 430072)
  • Received:2010-08-08 Revised:2011-04-01 Published:2011-04-12

PDF

2130

被引次数

16 | 4

近年来, 科学家们通过引进杂环片段、采用双(或多)官能化以及运用分子间弱相互作用等方法, 在二阶非线性光学发色团的性能优化方面取得了较大进展. 结合本课题组的研究, 对此领域的研究进行了较全面的综述, 并特别针对“非线性-透光性”矛盾的解决途径进行了较为详细的介绍.

关键词: 二阶非线性光学效应, 有机发色团, 分子一阶超极化率, 透明性

Second-order nonlinear optical (NLO) materials have played a very important role in laser technology since the invention of laser. As to the organic NLO materials, the chromophores are the key component. To tune the nonlinearity-transparency trade-off in organic NLO chromophores, several promising strategies were attempted, including the introduction of heterocyclic rings, dual (mutiple) functionalizations and utilization of the interactions between chromophore moieties. In this article, recent progress in this field is reviewed.

Key words: second-order nonlinear optical effect, chromophore, molecular first-order hyperpolarizability, transparency