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有机化学
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有机化学 ›› 1987, Vol. 7 ›› Issue (5): 357-361. 上一篇    下一篇

研究论文

固-液相转移催化合成IV.α-甲基丝氨酸及其它氨基酸

邬胜德;刘桂兰;陈代谟;蒋耀忠   

  1. 中国科学院成都有机化学研究所
  • 发布日期:1987-10-25

Solid-liquid phase transfer catalytic synthesis IV. \a\-methyl serine and other amino acids

WU SHENGDE;LIU GUILAN;CHEN DAIMO;JIANG YAOZHONG   

  • Published:1987-10-25

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338

关键词: 氨基酸, 水解, 烷基化, 相转移催化, 氯化铵, 苯甲醛, 席夫碱, 甘氨酸, 丝氨酸

Seven amino acids, including serine and a-methylserine, were synthesized under mild solid-liq. phase transfer catalytic conditions via alkylation of the Schiff base produced from reaction of glycine Et ester or alanine Me ester with benzaldehyde.

Key words: AMINO ACID, HYDROLYSIS, ALKYLATION, PHASE TRANSFER CATALYSIS, AMMONIUM CHLORIDE, BENZALDEHYDE, SCHIFF BASE, GLYCINE, SERINE

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