SIOC English
有机化学
高级检索

有机化学 ›› 2003, Vol. 23 ›› Issue (12): 1366-1369. 上一篇    下一篇

研究论文

二甲氧基嘧啶胺与金属配合物的恒容燃烧热测定

杨旭武;陈三平;高胜利;史启祯   

  1. 西北大学化学系
  • 发布日期:2003-12-25

Determination of Constant-Volume Combustion Heat for the Complexes of Metallic Salts with AMP

Yang Xuwu;Chen Sanping;Gao Shengli;Shi Qizhen   

  1. Shaanxi Key Labortory of physico-inorganic Chemistry,Department of Chemistry,Northwest University
  • Published:2003-12-25

PDF

477

在无水乙醇中，使钴、铜、锌、锰的盐与二甲氧基嘧啶胺(AMP)反应，回流数 小时后，浓缩、冷却，抽滤，制得了6种二甲氧基嘧啶胺与钴、铜、锌、锰的固态 配合物．用化学分析和元素分析确定了它们的组成，分别为Co(AMP)_2Cl_2(1)， Cu(AMP)_2Cl_2(2)，Cu(AMP)_2(NO_3)_2(3)，Zn(AMP)_2Cl_2(4)，Mn(AMP) _2Cl_2(5)和zn(AMP)s04(6)；用IR，～1H NMR研究了他们的成键情况；用精密转动 弹热量计测定了配体及配合物的恒容燃烧热△_cU，计算了它们的标准摩尔燃烧焓 △_cH_m～θ和标准摩尔生成焓△fH_m～θ．

关键词: 嘧啶 P;生成焓;元素分析;钴络合物;铜络合物;锌络合物;锰络合物, 元素分析

Six solid complexes of cobalt, copper, zinc and manganese with 2- amino-4, 6-dimethoxy-pyramidine (AMP) were prepared from AMP reacting with metal salts in absolute ethanol through reflux, concentration, cooling to room temperature and filtration. The composition of the complexes was determined by chemical and elemental analyses as Co(AMP) 2Cl2 (1), Cu(AMP)_2Cl_2 (2), Cu(AMP)_2(N0_3)_2 (3), Zn(AMP)_2Cl_2 (4), Mn(AMP)_2Cl_2 (5) and Zn(AMP)SO_4 (6) . The bonding characterization of the title complexes was investigated by IR and 'H NMR spectra. The constant-volume combustion heat of the ligand and the complexes (△_cU) was determined by a precision rotating bomb calorimeter at 298.15 K. Their standard molar combustion enthalpy (△_cH_m~θ) and standard molar enthalpy of formation (△_fH_m~θ) were calculated.

Key words: PYRIMIDINE P;ENTHALPY OF FORMATION;ELEMENTAL ANALYSIS;COBALT COMPLEX, COPPER COMPLEX;ZINC COMPLEX;MANGANESE COMPLEX;ELEMENTAL ANALYSIS

中图分类号: