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有机化学
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有机化学 ›› 2003, Vol. 23 ›› Issue (3): 277-280. 上一篇    下一篇

研究论文

二硫二茂铁的合成及其晶体结构

路军;李明;白银娟;胡怀明   

  1. 西北大学化学系;中国科学院化学研究所
  • 发布日期:2003-03-25

Synthesis and Crystal Structure of Diferrocenyl Disulfide

Lu Jun;Li Ming;Bai Yinjuan;Hu Huaiming   

  1. Department of Chemistry,Northwoest University,;Institute of Chemistry,Chinese Academy of Sciences
  • Published:2003-03-25

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被引次数

1

用AlI3作还原剂，还原二茂铁磺酰氯得到二硫二茂铁。通过元素分析，IR， ^1H NMR和^13C NMR对化合物进行了表征。用X射线单晶衍射法测定了该化合物的晶 体结构。结果表明，晶体属单斜晶系，P21空间群，a=0.61881（4）nm，b=0.3232 （9）nm，c=1.39056(11)nm，β=94.179（3）°，V=0.85593（12）nm^3，Dc=1. 628g/cm^3，μ=1.870mm^-1，F(000)=444，Z=2，R1=0.027，ωR2=0.0678。

关键词: 二茂铁;元素分析;红外分光光度法;质子磁共振谱法;碳13核磁共振谱法, X射线衍射分析;晶体结构;硫化合物

Diferrocenyl disuMide was synthesized by the reduction of ferrocenesulfonyl chloride using aluminum iodide as a reducing reagent. The structure was characterized by elemental analysis, IR, 'H NMR and 13C NMR spectra. Crystal structure was determined by X-ray diffraction analysis. The crystal data belong to monoclinic space group with unit cell dimensions a =0.61881 (4) nm, b = 1.03231(9) nm, c = 1.39056(11) nm, β= 94.179(3)°, V = 0.85593(12) nm~3, D-c = 1.628 g/cm~3, μ= 1. 870 mm~-1, F(000)=444, Z =2, R-1 =0.027 and wR-2 = 0.0678.

Key words: FERROCENE P;ELEMENTAL ANALYSIS;IR;1HNMR;C13NMR;XRD;CRYSTAL STRUCTURE, SULFUR COMPOUNDS

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