3-戊烯腈在零价镍催化体系中的平衡反应

doi:10.6023/cjoc1107202

有机化学 ›› 2012, Vol. ›› Issue (03): 627-631.DOI: 10.6023/cjoc1107202 上一篇下一篇

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3-戊烯腈在零价镍催化体系中的平衡反应

董建勋^a,b, 石玉坤^a, 胡晓静^a, 冯晓燕^b, 宋娟娟^a, 丁真贞^a, 刘向明^a, 黄唯平^a

a 南开大学化学系天津 300071;
b 中国平煤神马能源化工集团尼龙化工公司平顶山 467013

收稿日期:2011-07-20 修回日期:2011-10-25 发布日期:2012-03-24
通讯作者: 黄唯平 E-mail:huangw@eyou.com
基金资助:
国家自然科学基金(No. 21071086)资助项目.

Nickel(0)-Catalyzed Equilibrium Reaction of 3-Pentenenitrile

Dong Jianxun^a,b, Shi Yukun^a, Hu Xiaojing^a, Feng Xiaoyan^b, Song Juanjuan^a, Ding Zhenzhen^a

a College of Chemistry, Nankai University, Tianjin 300071;
b China Pingmei Shenma Energy and Chemical Group Nylon Chemical Company, Pingdingshan 467013

Received:2011-07-20 Revised:2011-10-25 Published:2012-03-24
Supported by:
Project supported by the National Natural Science Foundation of China (No. 21071086).

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摘要/Abstract

在探索3-戊烯腈氢氰化合成己二腈反应的机理过程中, 发现3-戊烯腈在零价镍体系中可能同时存在多个平衡反应, 在不外加氰化氢条件下, 3-戊烯腈可以生成甲基戊二腈和己二腈. 采用零价镍、膦配体和无水ZnCl₂ 组成的催化体系研究了该反应过程, 考察了反应温度和配体的影响, 并采用原位红外对反应进行监测, 提出了可能的反应机理.

关键词: 零价镍, 3-戊烯腈, 2-甲基戊二腈, 己二腈, 反应平衡

The equilibrium reaction of 3-pentenenitrile was carried out in the system containing Ni(0), P-ligand and anhydrous ZnCl₂. The equilibrium state of 3-pentenenitrile was affected by factors such as reaction temperatures and different ligands, which were investigated. The FTIR-ATR was used to monitor the reaction process of 3-pentenenitrile turning into 2-methylglutaronitrile and adiponitrile in absence of HCN and the possible reaction mechanism was proposed.

Key words: zero-valent nickel, 3-pentenenitrile, 2-methylglutaronitrile, adiponitrile, reaction equilibrium

引用此文

董建勋, 石玉坤, 胡晓静, 冯晓燕, 宋娟娟, 丁真贞. 3-戊烯腈在零价镍催化体系中的平衡反应[J]. 有机化学, 2012, (03): 627-631.

Dong Jianxun, Shi Yukun, Hu Xiaojing, Feng Xiaoyan, Song Juanjuan, Ding Zhenzhen, Liu Xiangming, HuangWeiping. Nickel(0)-Catalyzed Equilibrium Reaction of 3-Pentenenitrile[J]. Chin. J. Org. Chem., 2012, (03): 627-631.

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3-戊烯腈在零价镍催化体系中的平衡反应

Nickel(0)-Catalyzed Equilibrium Reaction of 3-Pentenenitrile

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