黄山药根茎中一个新睡茄内酯苷

doi:10.6023/cjoc201301083

有机化学 ›› 2013, Vol. 33 ›› Issue (06): 1349-1351.DOI: 10.6023/cjoc201301083 上一篇下一篇

研究简报

黄山药根茎中一个新睡茄内酯苷

单晓庆^a,b, 梁健^a, 丁立生^a, 王晓玲^b, 彭树林^a

a 中国科学院成都生物研究所山地生态恢复与生物资源利用重点实验室成都 610041;
b 西南民族大学少数民族药物研究所成都 610041

收稿日期:2013-02-01 修回日期:2013-03-06 发布日期:2013-03-28
通讯作者: 彭树林, 王晓玲 E-mail:pengsl@cib.ac.cn;wxl3232@sina.com
基金资助:
国家自然科学基金(Nos.30973634, 21072185)资助项目.

A Novel Withanolide Glucoside from the Rhizomes of Dioscorea panthaica

Shan Xiaoqing^a,b, Liang Jian^a, Ding Lisheng^a, Wang Xiaoling^b, Peng Shulin^a

a Key Laboratory of Mountain Ecological Restoration and Bioresource Utilization, Chengdu Institute of Biology, Chinese Academy of Sciences, Chengdu 610041;
b Ethnic Pharmaceutical Institute, Southwest University for Nationalities, Chengdu 610041

Received:2013-02-01 Revised:2013-03-06 Published:2013-03-28
Supported by:
Project supported by the National Natural Science Foundation of China (Nos.30973634, 21072185).

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摘要/Abstract

从地奥心血康原料药材黄山药根茎中分离得到一个结构新颖的微量成分.其结构通过包括2-D NMR在内的波谱分析确定为葡萄糖基接在内酯环上的多氧化withanolide型麦角甾内酯皂苷, 命名为薯蓣内酯葡糖苷.

关键词: 黄山药, 睡茄内酯苷, 薯蓣内酯葡糖苷

A novel withanolide type C₂₈-steroid saponin, named dioscolide glucoside, was isolated from the rhizomes of Dioscorea panthaica Prain et Buckill.The structure was elucidated as (20S,22R,24R,25S)-1-oxo-2α,3α;6α,7α-diepoxy-5α,16α,25α-trihydroxy-withanolide-27-O-glucopyranoside by spectroscopic evidence including 2D-NMR.

Key words: Dioscorea panthaica, withanolide glucoside, dioscolide glucoside

引用此文

单晓庆, 梁健, 丁立生, 王晓玲, 彭树林. 黄山药根茎中一个新睡茄内酯苷[J]. 有机化学, 2013, 33(06): 1349-1351.

Shan Xiaoqing, Liang Jian, Ding Lisheng, Wang Xiaoling, Peng Shulin. A Novel Withanolide Glucoside from the Rhizomes of Dioscorea panthaica[J]. Chin. J. Org. Chem., 2013, 33(06): 1349-1351.

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黄山药根茎中一个新睡茄内酯苷

A Novel Withanolide Glucoside from the Rhizomes of Dioscorea panthaica

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