有机化学 ›› 2015, Vol. 35 ›› Issue (5): 1152-1155.DOI: 10.6023/cjoc201411005 上一篇    下一篇

研究简报

基于5-氯-2-甲基噻吩的新型俘精酸酐的合成及其光致变色性能测定

贡志慧, 胡炳成, 余传明   

  1. 南京理工大学化工学院 南京 210094
  • 收稿日期:2014-11-14 修回日期:2014-12-25 发布日期:2015-01-09
  • 通讯作者: 胡炳成 E-mail:hubingcheng210094@163.com

Synthesis and Photochromic Properties of Novel Fulgide Based on 5-Chloro-2-methylthiophene

Gong Zhihui, Hu Bingcheng, Yu Chuanming   

  1. School of Chemical Engineering, Nanjing University of Science & Technology, Nanjing 210094
  • Received:2014-11-14 Revised:2014-12-25 Published:2015-01-09

针对杂环俘精酸酐良好的光致变色性能, 以2-甲基噻吩和丁二酸二乙酯为原料, 经过氯代、乙酰化、Stobbe缩合等反应合成了(E)-2-[1-(5-氯-2-甲基噻吩-3-基)乙亚基]-3-异丙亚基丁二酸酐, 其结构经1H NMR, 13C NMR, MS表征确认; 初步考察了在不同的光照时间下目标产物的光致变色性能.

关键词: 俘精酸酐, 光致变色, Stobbe缩合

The good photochromic properties was the new target of heterocyclic fulgides development. The new compound, (E)-2-[1-(5-chloro-2-methylthiophen-3-yl)ethylidene]-3-isopropylidene succinic anhydride, was synthesized using 2-methyl- thiophene and diethyl succinate as the starting materials by steps of chlorination, acetylation and Stobbe condensations, and its structure was fully characterized by 1H NMR, 13C NMR and MS techniques. The photochromic properties of the target product were studied under the different illumination time.

Key words: fulgide, photochromism, Stobbe condensations