有机化学 ›› 2015, Vol. 35 ›› Issue (6): 1270-1275.DOI: 10.6023/cjoc201412021 上一篇    下一篇

研究论文

碳负载铜一锅法催化合成苯并硒唑类衍生物

周美云a, 吴照钧a, 李毅群a, 郑文杰a, 纪盛滨a, 周华b   

  1. a 暨南大学化学系 广州 510632;
    b 暨南大学理工学院食品科学与工程系 广州 510632
  • 收稿日期:2014-12-12 修回日期:2015-01-20 发布日期:2015-02-10
  • 通讯作者: 周华 E-mail:zhhua-1@163.com
  • 基金资助:

    国家自然科学基金(Nos. 31101323, 31000816)资助项目.

One-Pot Synthesis of Benzo[d][1,3]selenazole Derivatives by Using Carbon-Supported Copper Catalyst

Zhou Meiyuna, Wu Zhaojuna, Li Yiquna, Zheng Wenjiea, Ji Shengbina, Zhou Huab   

  1. a Department of Chemistry, Jinan University, Guangzhou 510632;
    b Department of Food Science and Engineering, Jinan University, Guangzhou 510632
  • Received:2014-12-12 Revised:2015-01-20 Published:2015-02-10
  • Supported by:

    Project supported by the National Natural Science Foundation of China (Nos. 31101323, 31000816).

建立了一种简单实用、经济高效的以邻溴苯胺为起始原料, 廉价的活性碳负载铜为催化剂, 在室温条件下一锅法合成苯并硒唑类衍生物的方法, 得到了中等到优良的产率. 本方法具有催化剂廉价易得、操作简便、合成效率高的优点.

关键词: 一锅法合成, 苯并硒唑, 碳负载铜催化

A simple, efficient, inexpensive one-pot method for the benzo[d][1,3]selenazole derivatives synthesized from 2-bromoaniline was developed by using cheap carbon-supported copper as catalyst at room temperature. The reaction provides an efficient protocol to a series of benzo[d][1,3]selenazole derivatives in good to high yields, and benefits of readily available catalyst and synthesis of high efficiency.

Key words: one-pot synthesis, benzo[d][1,3]selenazole, carbon-supported copper