三甲基膦支持的硒配位钴氢配合物的合成和性质

doi:10.6023/cjoc201702047

有机化学 ›› 2017, Vol. 37 ›› Issue (6): 1392-1397.DOI: 10.6023/cjoc201702047 上一篇下一篇

研究论文

三甲基膦支持的硒配位钴氢配合物的合成和性质

栾化鑫, 孙宏建, 薛本静, 李晓燕

山东大学化学与化工学院教育部特种功能聚集体材料重点实验室济南 250199

收稿日期:2017-02-28 修回日期:2017-04-14 发布日期:2017-05-10
通讯作者: 李晓燕 E-mail:xli63@sdu.edu.cn
基金资助:
国家自然科学基金（No.21372143）资助项目.

Synthesis and Properties of a Se-Coordinated Hydrido Cobalt(III) Complex Supported by Trimethylphosphine

Luan Huaxin, Sun Hongjian, Xue Benjing, Li Xiaoyan

Key Laboratory of Special Functional Aggregated Materials, Ministry of Education, School of Chemistry and Chemical Engineering, Shandong University, Jinan 250199

Received:2017-02-28 Revised:2017-04-14 Published:2017-05-10
Contact: 10.6023/cjoc201702047 E-mail:xli63@sdu.edu.cn
Supported by:
Project supported by the National Natural Science Foundation of China (No. 21372143).

文章分享

1. 三甲基膦支持的硒配位钴氢配合物的合成和性质.PDF(909KB)

摘要/Abstract

通过4-甲氧基苯硒酚和2-甲基苯硒酚分别与Co（PMe₃）₄反应生成了单核Co（II）配合物[Co（4-MeOC₆H₄Se）₂-（PMe₃）₃]（1）和双核Co（I）配合物[Co（PMe₃）₂（SeC₆H₄-2-Me）]₂ （2）.配合物2与CO作用形成了配合物[Co（PMe₃）₂（CO）₂（Se-C₆H₄-2-Me）]（3）.而苯硒酚与Co（PMe₃）₄反应制备了硒配位的钴氢配合物[mer-Co（H）（SePh）₂（PMe₃）₃]（4）和双核Co（I）配合物[Co（PMe₃）₂（SePh）]₂ （5）.初步研究表明4对于醛和酮的硅氢化反应有一定的催化效果.配合物1，3和4的分子结构通过X射线衍射进行了证实.

关键词: 钴氢配合物, 硒酚, 硒配位, 硅氢化反应, 羰基钴配合物

A mononuclear cobalt(II) complex[Co(4-MeOC₆H₄Se)₂(PMe₃)₃] (1) and a dinuclear cobalt diphenylselenolato complex[Co(PMe₃)₂(SeC₆H₄-2-Me)]₂ (2) were obtained from the reaction of 4-methoxyselenophenol and 2-methylseleno-phenol with Co(PMe₃)₄, respectively. The dicarbonyl cobalt(I) complex[Co(PMe₃)₂(CO)₂(SeC₆H₄-2-Me)] (3) was formed through the reaction of complex 2 with carbon monoxide. A novel selenophenolato hydridocobalt(III) complex[mer-Co(H)(SePh)₂(PMe₃)₃] (4) and a dinuclear cobalt diphenylselenolato complex[Co(PMe₃)₂(SePh)]₂ (5) were synthesized by the reaction of selenophenol with Co(PMe₃)₄. It was found that complex 4 could catalyze the hydrosilylation of aldehydes and ketones. The molecular structures of 1, 3 and 4 were determined by X-ray diffraction.

Key words: hydrido cobalt complex, selenophenol, Se-coordinated, hydrosilylation, carbonyl cobalt complex

引用此文

栾化鑫, 孙宏建, 薛本静, 李晓燕. 三甲基膦支持的硒配位钴氢配合物的合成和性质[J]. 有机化学, 2017, 37(6): 1392-1397.

Luan Huaxin, Sun Hongjian, Xue Benjing, Li Xiaoyan. Synthesis and Properties of a Se-Coordinated Hydrido Cobalt(III) Complex Supported by Trimethylphosphine[J]. Chin. J. Org. Chem., 2017, 37(6): 1392-1397.

导出引用 EndNote|Reference Manager|ProCite|BibTeX|RefWorks

分享此文

参考文献

[1] Bauer, I.; Knölker, H. J. Chem. Rev. 2015, 115, 3170.
[2] Wang, W. H.; Himeda, Y.; Muckerman, J. T.; Manbeck, G. F.; Fujita, E. Chem. Rev. 2015, 115, 12936.
[3] Eberhardt, N. A.; Guan, H. R. Chem. Rev. 2016, 116, 8373.
[4] Guo, N.; Zhu, S. F. Chin. J. Org. Chem. 2015, 35, 1383 (in Chinese). (郭娜, 朱守非, 有机化学, 2015, 35, 1383.)
[5] Yuan, Q. J.; Zhang, W. B. Chin. J. Org. Chem. 2015, 36, 274 (in Chinese). (袁乾家, 张万斌, 有机化学, 2015, 36, 274.)
[6] Zhang, H.; Sun, H. J.; Li, X. Y. Chin. J. Org. Chem. 2016, 36, 2843 (in Chinese). (仉花, 孙宏建, 李晓燕, 有机化学, 2016, 36, 2843.)
[7] Gunanathan, C.; Hölscher, M.; Pan, F.; Leitner, W. J. Am. Chem. Soc. 2012, 134, 14349.
[8] Jiang, Y.; Huang, W.; Schmalle, H. W.; Blacque, O.; Fox, T.; Berke, H. Organometallics 2013, 32, 7043.
[9] Dai, N.; Shang, R.; Fu, M. C.; Fu, Y. Chin. J. Chem. 2015, 33, 405.
[10] Liang, M. T.; Xia, X. F.; Liu, X.; Li, H. X. Chin. J. Chem. 2015, 33, 578.
[11] Yang, X. ACS Catal. 2012, 2, 964.
[12] Huff, C. A.; Sanford, M. S. ACS Catal. 2013, 3, 2412.
[13] Hu, P.; Diskin-Posner, Y.; Ben-David, Y.; Milstein, D. ACS Catal. 2014, 4, 2649.
[14] Arndtsen, B. A.; Bergman, R. G. Science 1995, 270, 1970.
[15] Li, C.; Widjaja, E.; Garland, M. Organometallics 2004, 23, 4131.
[16] Filonenko, G. A.; Hensen, E. J.; Pidko, E. A. Catal. Sci. Technol. 2014, 4, 3474.
[17] McGrady, G. S.; Guilera, G. Chem. Soc. Rev. 2003, 32, 383.
[18] Conifer, C.; Gunanathan, C.; Rinesch, T.; Hölscher, M.; Leitner, W. Eur. J. Inorg. Chem. 2015, 333.
[19] Chen, H.; Schlecht, S.; Semple, T. C.; Hartwig, J. F. Science 2000, 287, 1995.
[20] Hauwert, P.; Boerleider, R.; Warsink, S.; Weigand, J. J.; Elsevier, C. J. J. Am. Chem. Soc. 2010, 132, 16900.
[21] Fan, L.; Parkin, S.; Ozerov, O. V. J. Am. Chem. Soc. 2005, 127, 16772.
[22] Lersch, M.; Tilset, M. Chem. Rev. 2005, 105, 2471.
[23] Haenel, M. W.; Oevers, S.; Angermund, K.; Kaska, W. C.; Fan, H. J.; Hall, M. B. Angew. Chem. 2001, 113, 3708.
[24] Nielsen, M.; Alberico, E.; Baumann, W.; Drexler, H. J.; Junge, H.; Gladiali, S.; Beller, M. Nature 2013, 495, 85.
[25] Clarke, Z. E.; Maragh, P. T.; Dasgupta, T. P.; Gusev, D. G.; Lough, A. J.; Abdur-Rashid, K. Organometallics 2006, 25, 4113.
[26] Jiang, Y.; Blacque, O.; Fox, T.; Frech, C. M.; Berke, H. Organo-metallics 2009, 28, 5493.
[27] Guo, R.; Lough, A. J.; Morris, R. H.; Song, D. Organometallics 2004, 23, 5524.
[28] Burling, S.; Kociok-Köhn, G.; Mahon, M. F.; Whittlesey, M. K.; Williams, J. M. Organometallics 2005, 24, 5868.
[29] Jones, W. D. Inorg. Chem. 2005, 44, 4475.
[30] Fu, X.; Wayland, B. B. J. Am. Chem. Soc. 2005, 127, 16460.
[31] Li, X.; Chianese, A. R.; Vogel, T.; Crabtree, R. H. Org. Lett. 2005, 7, 5437.
[32] Ding, K.; Brennessel, W. W.; Holland, P. L. J. Am. Chem. Soc. 2009, 131, 10804.
[33] Du, J. Z.; Wang, L. B.; Xie, M. H.; Deng, L. Angew. Chem., Int. Ed. 2015, 54, 12640.
[34] Sun, J.; Luo, L.; Luo, Y.; Deng, L. Angew. Chem., Int. Ed. 2017, 56, 2720.
[35] Scheuermann, M. L.; Semproni, S. P.; Pappas, I.; Chirik, P. J. Inorg. Chem. 2014, 53, 9463.
[36] Tokmic, K.; Markus, C. R.; Zhu, L.; Fout, A. R. J. Am. Chem. Soc. 2016, 138, 11907.
[37] Jeletic, M. S.; Helm, M. L.; Hulley, E. B.; Mock, M. T.; Appel, A. M.; Linehan, J. C. ACS Catal. 2014, 4, 3755.
[38] Yu, R. P.; Darmon, J. M.; Milsmann, C.; Margulieux, G. W.; Stieber, S. C. E.; DeBeer, S.; Chirik, P. J. J. Am. Chem. Soc. 2013, 135, 13168.
[39] Niu, Q.; Sun, H.; Li, X.; Klein, H.-F.; Flörke, U. Organometallics 2013, 32, 5235.
[40] Zhou, H.; Sun, H.; Zhang, S.; Li, X. Organometallics 2015, 34, 1479.
[41] Xiong, Z.; Li, X.; Zhang, S.; Shi, Y.; Sun, H. Organometallics 2016, 35, 357.
[42] Jiao, G.; Li, X.; Sun, H.; Xu, X. J. Organomet. Chem. 2007, 692, 4251.
[43] Foster, D. G. Org. Synth. 1944, 24, 89.
[44] Klein, H.-F.; Karsch, H. H. Chem. Ber. 1975, 108, 944.
[45] Dolomanov, O. V.; Bourhis, L. J.; Gildea, R. J.; Howard, J. A. K.; Puschmann, H. J. Appl. Crystallogr. 2009, 42, 339.
[46] Sheldrick, G. M. Acta Crystallogr. 2008, A64, 112.
[47] Sheldrick, G. M. Acta Crystallogr. 2015, C71, 3.

三甲基膦支持的硒配位钴氢配合物的合成和性质

Synthesis and Properties of a Se-Coordinated Hydrido Cobalt(III) Complex Supported by Trimethylphosphine

PDF

补充材料

可视化

被引次数

摘要/Abstract

引用此文

分享此文

参考文献

相关文章 9

编辑推荐

相关统计

本文评价

[1]	冯向青, 杜海峰. B(C₆F₅)₃催化不饱和烃的硅化反应[J]. 有机化学, 2023, 43(10): 3544-3557.
[2]	郑婷婷, 王洋洋, 杨在孝, 孙宏建, 李晓燕. 铁氢配合物对一级酰胺脱水成腈的催化作用[J]. 有机化学, 2019, 39(10): 2941-2945.
[3]	吴慧, 白赢, 厉嘉云, 胡应乾, 彭家建, 邱化玉, 来国桥. 过渡金属膦配合物在硅氢化反应中的应用研究[J]. 有机化学, 2009, 29(12): 1899-1905.
[4]	唐新德, 张其震, 侯昭升, 李爱香, 周其凤. 新型树状大分子核醚-四硅烷的合成[J]. 有机化学, 2004, 24(1): 103-105.
[5]	姚金水,吴佑实. 催化不对称硅氧化反应研究进展[J]. 有机化学, 2002, 22(2): 101-106.
[6]	雷耀辉,李弘,何炳林. 手性金属配合物催化的前手性羰基化合物的不对称硅氢化反应研究进展[J]. 有机化学, 2000, 20(4): 464-469.
[7]	方鹏飞,陈远荫,王中华,卢秋生. C~6~0乙醇胺铂配合物的合成及其催化硅氢化性能[J]. 有机化学, 1999, 19(6): 600-605.
[8]	姚金水,刘丹凤,李弘,何炳林. 手性2-(2-吡啶基)-4-羧乙基-1, 3-噻唑烷的合成及应用研究[J]. 有机化学, 1998, 18(4): 372-376.
[9]	李树春,徐善生,周秀中. ａ,β不饱和醛的均相催化氢硅化反应[J]. 有机化学, 1992, 12(5): 497-501.