膦烯化合物的合成及应用研究进展

doi:10.6023/cjoc201811038

摘要/Abstract

含有P＝C双键膦烯化合物在均相催化、有机光伏材料、有机光电材料和纳米功能材料等领域有着重要的潜在应用价值，但是由于合成难度大和结构稳定性差等原因，其研究进展一直较为缓慢.从膦烯化合物的性质、合成方法及应用等方面系统总结了近几十年来膦烯化合物的研究进展，为从事相关研究的科学家提供参考.

关键词: 低配位有机磷, P=C双键, 膦烯, 磷杂苯

The phosphaalkenes, as an important part of organophosphorus chemistry, play a very important role in the field of homogeneous catalysis and functional materials due to special properties of P=C unit. However, the difficult access to phosphaalkene compounds and their less stability have severely retarded the progress of the phosphaalkene chemistry. In this paper, the recent advances in phosphaalkenes, introducing the properties, synthetic methods, and applications of phosphaalkenes to provide some reference for related researcher are reviewed.

Key words: low coordination phosphorus, P=C double bond, phosphaalkene, phosphinine

引用此文

黄海洋, 丁海新, 徐双双, 柏江, 肖强. 膦烯化合物的合成及应用研究进展[J]. 有机化学, 2019, 39(5): 1263-1276.

Huang Haiyang, Ding Haixin, Xu Shuangshuang, Bai Jiang, Xiao Qiang. Progress in the Synthesis and Applications of Phosphaalkenes[J]. Chin. J. Org. Chem., 2019, 39(5): 1263-1276.

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