有机化学 ›› 2021, Vol. 41 ›› Issue (7): 2587-2600.DOI: 10.6023/cjoc202102014 上一篇    下一篇

综述与进展

芳基三氮烯作为芳基前体和芳基偶氮前体在有机合成中的应用研究进展

张永红a,b,*(), 唐承宗a, 刘永红a, 刘晨江a,b,*()   

  1. a 新疆大学化学学院 省部共建碳基能源资源化学与利用国家重点实验室 石油天然气精细化工教育部&自治区重点实验室 乌鲁木齐绿色催化与合成技术重点实验室 乌鲁木齐 830046
    b 北京分子科学国家研究中心 北京 100871
  • 收稿日期:2021-02-02 修回日期:2021-03-23 发布日期:2021-04-16
  • 通讯作者: 张永红, 刘晨江
  • 基金资助:
    新疆维吾尔自治区自然科学基金(2017D01C035); 国家自然科学基金(21762041); 国家自然科学基金(21861036)

Research Progress of Aryltriazene as Aryl Precursor and Aryl-Azo Precursors in Organic Synthesis

Yonghong Zhanga,b(), Chengzong Tanga, Yonghong Liua, Chenjiang Liua,b()   

  1. a State Key Laboratory of Chemistry and Utilization of Carbon Based Energy Resources, Key Laboratory of Oil and Gas Fine Chemicals, Ministry of Education & Xinjiang Uygur Autonomous Region, Urumqi Key Laboratory of Green Catalysis and Synthesis Technology, College of Chemistry, Xinjiang University, Urumqi, Xinjiang 830046
    b Beijing National Laboratory for Molecular Sciences, Beijing 100871
  • Received:2021-02-02 Revised:2021-03-23 Published:2021-04-16
  • Contact: Yonghong Zhang, Chenjiang Liu
  • Supported by:
    Natural Science Foundation of Xinjiang Uyghur Autonomous Region(2017D01C035); National Natural Science Foundation of China(21762041); National Natural Science Foundation of China(21861036)

芳基三氮烯因制备简单, 稳定性好, 反应位点多, 反应条件温和等优点, 作为一种稳定的芳基重氮盐替代物被广泛用于有机合成中. 主要综述了近年来以芳基三氮烯作为芳基前体和芳基偶氮前体在有机合成中的应用研究进展.

关键词: 芳基三氮烯, 芳基前体, 芳基偶氮前体, 有机合成方法学

Aryltriazenes have been widely used as a stable aryldiazonium salt surrogate in organic synthesis, in which the compounds show advantages of easy preparation, good stability, multiple reaction sites and mild reaction conditions. In this review, the recent advances in the application of aryltriazenes in organic synthesis as aryl or aryl azo precursors are reviewed.

Key words: aryl triazene, aryl precursor, aryl azo precursor, organic synthetic methodology