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有机化学
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有机化学 ›› 2004, Vol. 24 ›› Issue (9): 1086-1090. 上一篇    下一篇

研究论文

对叔丁基杯[8]芳烃/12-钨(钼)磷(硅)杂多酸超分子包合物的合成与性质

李明轩a, 柳利*,b, 柳士忠b   

  1. a湖北大学化工厂 武汉 430062;
    b湖北大学化学与材料科学学院 武汉 430062
  • 收稿日期:2003-11-24 修回日期:2004-07-14 接受日期:2004-07-14 发布日期:2022-09-20
  • 基金资助:
    湖北省自然科学基金(No. 01ABB088)资助项目.

Synthesis and Properties of tert-Butyl Calix[8]arene/12-Tungstic(molybdic) Phospho(silico) Heteropolyacid Supermolecular Inclusion Complexes

LI Ming-Xuana, LIU Li*,b, LIU Shi-Zhongb   

  1. aFactory of Chemical Industry, Hubei University, Wuhan 430062;
    bFaculty of Chemistry and Material Science, Hubei University, Wuhan 430062
  • Received:2003-11-24 Revised:2004-07-14 Accepted:2004-07-14 Published:2022-09-20
  • Contact: * E-mail: lisz@public.wh.hb.cn

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用自识别自组装法合成了三种新型对叔丁基杯[8]芳烃/12-钨(钼)磷(硅)杂多酸超分子包合物,C88H115～116O8 [XM12~O40] (X=P, Si; M=W, Mo),用元素分析,IR, UV, 1H NMR, 31P NMR, ESR, XPS, Fluorescence光谱进行了表征.结果表明,对叔丁基杯[8]芳烃主体化合物与12-钨(钼)磷(硅)杂多酸客体分子发生了主-客体包合反应,生成了稳定的发光包合物.

关键词: 12-钨(钼)磷(硅)杂多酸, 对叔丁基杯[8]芳烃, 超分子自组装, 发光包合物

Three new tert-butyl calix[8]arene/12-tungstic(molybdic) phospho(silico) heteropolyacid supermolecular complexes have been synthesized by self-recognition and self-assembly method, and characterized byelemental analysis, IR, UV, 1H NMR, 31P NMR, ESR, XPS and fluorescence spectra. The results indicated that the stable inclusion complexes were formed. The host-guest inclusion reaction occurred between tert-butyl calix[8]arene host and 12-tungstic(molybdic) phospho(silico) guest.

Key words: 12-tungstic(molybdic) phospho(silico) heteropolyacid, tert-butyl calix[8]arene, supermolecular self-assembly, inclusion complex