一类新基元反应的发现: 金/铑杂克莱森重排

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杨吉民, 薛小松^*()

Jimin Yang, Xiaosong Xue()

CAS Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032

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杨吉民, 薛小松. 一类新基元反应的发现: 金/铑杂克莱森重排[J]. 有机化学, 2023, 43(4): 1598-1599.

Jimin Yang, Xiaosong Xue. A New Elementary Reaction: Au/Ru-Claisen Rearrangement[J]. Chinese Journal of Organic Chemistry, 2023, 43(4): 1598-1599.

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图式1. 克莱森重排和金属杂克莱森重排

Scheme 1. Claisen rearrangement and metalla-Claisen rearrangement

图式2. 金或铑催化[4＋2]反应的金属杂克莱森重排路径

Scheme 2. Metalla-Claisen rearrangement pathway of Au or Rh catalyzed [4＋2] reaction

图式3. 金属杂克莱森重排过程中关键中间体的波函数分析及内禀键轨道分析[5]

Scheme 3. Wavefunction analysis of key intermediates and IBO analysis along the metalla-Claisen rearrangement process

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