光促进的串联σ-重排反应合成多取代1,3-共轭二烯

doi:10.6023/cjoc202400029

有机化学 ›› 2024, Vol. 44 ›› Issue (6): 2049-2050.DOI: 10.6023/cjoc202400029 上一篇下一篇

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光促进的串联σ-重排反应合成多取代1,3-共轭二烯

徐毅栲^a,†, 王泽树^b,†, 何卫民^a^,^*(), 叶龙武^a^,^b^,^*()

a 南华大学化学化工学院湖南衡阳 421001
b 厦门大学化学化工学院福建厦门 361005

发布日期:2024-07-08
作者简介:
^†共同第一作者

Photo-Promoted Cascade Sigmatropic Rearrangement Reaction for the Synthesis of Polysubstituted 1,3-Conjugated Dienes

Yikao Xu^a,†, Zeshu Wang^b,†, Weimin He^a,*(), Longwu Ye^a^,^b,*()

a College of Chemistry and Chemical Engineering, University of South China, Hengyang, Hunan 421001
b College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, Fujian 361005

Published:2024-07-08
Contact: * E-mail: weiminhe@usc.edu.cn; longwuye@xmu.edu.cn.
About author:
^†These authors contributed equally to this work.

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徐毅栲, 王泽树, 何卫民, 叶龙武. 光促进的串联σ-重排反应合成多取代1,3-共轭二烯[J]. 有机化学, 2024, 44(6): 2049-2050.

Yikao Xu, Zeshu Wang, Weimin He, Longwu Ye. Photo-Promoted Cascade Sigmatropic Rearrangement Reaction for the Synthesis of Polysubstituted 1,3-Conjugated Dienes[J]. Chinese Journal of Organic Chemistry, 2024, 44(6): 2049-2050.

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图式1. 光促进的串联σ-重排反应

Scheme 1. Photo-promoted cascade sigma-tropic rearrangement reaction

图1. 药物及天然产物的后期官能团化

Figure 1. Post-functionalization of drugs and natural products

图式2. 光促进的串联σ-重排反应的可能机理

Scheme 2. Proposed mechanism for the photo-promoted cascade sigmatropic rearrangement

参考文献 9

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[5]	Hashimoto, T.; Maruoka, K. Chem. Rev. 2015, 115, 5366.
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[8]	Machiguchi, T.; Okamoto, J.; Morita, Y.; Hasegawa, T.; Yamabe, S.; Minato, T. J. Am. Chem. Soc. 2006, 128, 44.
[9]	Ji, X.; Shen, C.; Ni, Y.; Si, Z.-Y.; Wang, Y.; Zhi, X.; Zhao, Y.; Peng, H.; Liu, L. Angew. Chem., Int. Ed. 2024, e202400805. Ciszewski, Ł. W.; Rybicka-Jasińska, K.; Gryko, D. Org. Biomol. Chem. 2019, 17, 432.

光促进的串联σ-重排反应合成多取代1,3-共轭二烯

Photo-Promoted Cascade Sigmatropic Rearrangement Reaction for the Synthesis of Polysubstituted 1,3-Conjugated Dienes

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