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2012 , Vol. 32 >Issue 04: 709 - 713

DOI: https://doi.org/10.6023/cjoc1110072

研究论文

meso-四(对烷氧基苯基)卟啉镁配合物的合成、表征和性能研究

  • 刘捷频 ,
  • 杨德亮 ,
  • 曹华 ,
  • 赵鸿斌
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  • a 湘潭职业技术学院医技学院 湘潭 411103;
    b 湘潭大学化学学院 湘潭 411105;
    c 广东德联集团股份有限公司 广东 510630

收稿日期: 2011-10-07

  修回日期: 2011-12-13

  网络出版日期: 2012-04-24

基金资助

湘潭市科研课题(No. JZ200811)和湖南省自然科学基金(No. 04JJ40013)资助项目.

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Synthesis, Characterization and Properties of Metallic Magnesium Complexes of meso-Tetrakis(4-alkoxyphenyl)porphyrins

  • Liu Jiepin ,
  • Yang Deliang ,
  • Cao Hua ,
  • Zhao Hongbin
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  • a Medical Technology Institute, Xiangtan Vocational & Technical College, Xiangtan 411103;
    b College of Chemistry, Xiangtan University, Xiangtan 411105;
    c Guangdong Delian Group Co., Ltd, Guangdong 510630

Received date: 2011-10-07

  Revised date: 2011-12-13

  Online published: 2012-04-24

Supported by

Project supported by the Scientific Research Project of Xiangtan of Hunan Province (No. JZ200811) and the Natural Science Foundation of Hunan Province of China (No. 04JJ40013).

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摘要

合成了一系列meso-四(对烷氧基苯基)卟啉镁配合物, 用UV-Vis, 1H NMR, IR, MS, 元素分析等确证了配合物的结构, 总结了镁与卟啉类配体配合的UV-Vis, 1H NMR, IR 数据. 采用差示扫描量热法(DSC)和偏光显微镜(PM)研究了该系列配合物的液晶性能, 发现6 个配合物具有液晶性; 考察了烷氧基链长、配位金属离子和分子空间结构对液晶性能的影响.

关键词： 卟啉镁配合物; 合成; 表征; 液晶性

本文引用格式

刘捷频 , 杨德亮 , 曹华 , 赵鸿斌 . meso-四(对烷氧基苯基)卟啉镁配合物的合成、表征和性能研究[J]. 有机化学, 2012 , 32(04) : 709 -713 . DOI: 10.6023/cjoc1110072

Abstract

A series of magnesium complexes of porphyrins were synthesized. Molecular structures of all synthesized compounds were confirmed by UV-Vis, 1H NMR, IR, MS techniques and elemental analysis. Characteristic spectrometric data of IR, UV-Vis, 1H NMR related to their structures have been systematically analyzed. Differential scanning calorimetry (DSC) and polarizing microscope (PM) were used to probe the liquid crystal properties of the serial complexes. Six of the serial complexes were found to exhibit liquid crystal properties. The effects of alkoxy chains, metal ions of complexes and molecular space structure on liquid crystal properties have been investigated.

Key words： magnesium complexes of porphyrin; synthesis; characterization; liquid crystal property

参考文献

[1] Zhao, S.-F.; Chen, N.-Y.; Guo, X.; Wang, M.-H.; Li, Z.-Y. Chin. J. Org. Chem. 2010, 30(12), 1898 (in Chinese). (赵胜芳, 陈年友, 郭鑫, 王孟华, 李早英, 有机化学, 2010, 30(12), 1898.)

[2] Wang. Z.-F.; Deng, W.-L. Prog. Chem. 2007, 19(4), 520 (in Chinese). (王周锋, 邓文礼, 化学进展, 2007, 19(4), 520.)

[3] Jurow, M.; Schuckman, A. E.; Batteas, J. D.; Drain, C. M. Coord. Chem. Rev. 2010, 254, 2297.  

[4] (a) Wang, H.-K.; Peng, S.-M.; Zhao, H.-B.; Xu, L.-L.; Zhang, H.; Lu, X.-J. Acta Chim. Sinica 2009, 67(14), 1643 (in Chinese). (王红科, 彭圣明, 赵鸿斌, 徐兰兰, 张辉, 陆旭甲, 化学学报, 2009, 67(14), 1643.) (b) Zhang, H.; Zhao, H.-B.; Lu, X.-J.; Wang, W.-L.; Chang, H.; Wang, Y.-F. Acta Chim. Sinica 2011, 69(3), 316 (in Chinese). (张辉, 赵鸿斌, 陆旭甲, 王武林, 常慧, 王玉芳, 化学学报, 2011, 69(3), 316.)

[5] (a) Zhao, H.-B.; Cai, J.; Lin, Y.-B.; Yang, N.-F.; Wang, X.-Y. Acta Chim. Sinica 2000, 58(5), 543 (in Chinese). (赵鸿斌, 蔡剑, 林原斌, 阳年发, 王霞瑜, 化学学报, 2000, 58(5), 543.) (b) Liu, J.-P.; Zhao, H.-B.; Xu, Y.-J.; Cao, H.; Chen, K. Chin. J. Org. Chem. 2007, 27(6), 778 (in Chinese). (刘捷频, 赵鸿斌, 徐勇军, 曹华, 陈科, 有机化学, 2007, 27(6), 778.) (c) Zhao, H.-B.; Luo, H.-A.; He, J.-P.; Peng, S.-M.; Xie, Q.-Y. Acta Chim. Sinica 2006, 64(4), 331 (in Chinese). (赵鸿斌, 罗和安, 贺江平, 彭圣明, 谢琼玉, 化学学报, 2006, 64(4), 331.) (d) He, J.-P.; Zhao, H.-B.; Chang, H.; Peng, S.-M.; Xie, Q.-Y.; Liu, J.-P. Chin. J. Org. Chem. 2006, 26(12), 1663 (in Chinese). (贺江平, 赵鸿斌, 常慧, 彭圣明, 谢琼玉, 刘捷频, 有机化学, 2006, 26(12), 1663.) (e) Xu, Y.-J.; Gu, Z.; Zhao, H.-B.; Wang, L.-S.; Ning, M.-X.; Qiu, S.-J. Chem. J. Chin. Univ. 2008, 29(10), 1930 (in Chinese). (徐勇军, 顾峥, 赵鸿斌, 王励申, 宁满侠, 仇诗军, 高等学校化 学学报, 2008, 29(10), 1930.)

[6] (a) Gregg, B. A.; Fox, A. J. J. Chem. Soc., Chem. Commun. 1987, 15, 1134. (b) Gregg, B. A.; Fox, M. A.; Bard, A. J. J. Am. Chem. Soc. 1989, 111, 3024.  

[7] Kugimiya, S.; Takemura, M. Tetrahedron Lett. 1990, 31(22), 3157.  

[8] Shimizu, Y.; Miya, M.; Nagata, A.; Ohta, K.; Yamamoto, I.; Kusabayashi, S. Liq. Cryst. 1993, 14(3), 795.  

[9] Castella, M.; López-Calahorra, F.; Velasco, D.; Finkelmann, H. Chem. Commun. 2002, 20, 2348.

[10] Liu, W.; Shi, T.-S. Sci. China, Ser. B: Chem. 2007, 50(4), 488.

[11] (a) Wang, Q. M.; Bruce, D. W. Angew. Chem., Int. Ed. Engl. 1997, 36, 150. (b) Ying, X.; Shi, J. Liq. Cryst. 2000, 27, 211. (c) Zhao, Z.-X.; Lin, G.-F. Liq. Cryst. 2002, 29(10), 1335. (d) Qi, M.-H.; Lin, G.-F. J. Phys. Chem. B 2003, 107(31), 7640.
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