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2012 , Vol. 32 >Issue 01: 156 - 159

DOI: https://doi.org/10.6023/cjoc1104071

研究简报

3-甲基-9-芳基-1,8-二氧代-2,10-二氧杂蒽衍生物的合成

  • 游新奎 ,
  • 林志兰 ,
  • 张雪利 ,
  • 高原
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  • 深圳大学化学与化工学院 深圳 518060

收稿日期: 2011-04-07

  修回日期: 2011-09-06

  网络出版日期: 2011-09-26

基金资助

国家自然科学基金(No. 81071144)和广东省自然科学基金(No. 9451806001002961)资助项目.

收起

Synthesis of 9-Aryl-3-methyl-1,8-dioxo-2,10-dioxanthens

  • YOU Xin-Kui ,
  • LIN Zhi-Lan ,
  • ZHANG Xue-Li ,
  • GAO Yuan
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  • College of Chemistry and Chemical Engineering, Shenzhen University, Shenzhen 518060

Received date: 2011-04-07

  Revised date: 2011-09-06

  Online published: 2011-09-26

Supported by

Project supported by the National Natural Science Foundation of China (No. 81071144) and the Natural Science Foundation of Guangdong Province (No. 9451806001002961).

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摘要

以芳醛、4-羟基-6-甲基-2-吡喃酮和1,3-环己二酮为原料, 乙二醇为溶剂合成了一系列3-甲基-9-芳基-1,8-二氧代-2,10-二氧杂蒽衍生物. 该反应产率高(70%～83%)、操作简单、后处理方便. 产物的结构经红外光谱、核磁共振谱及单晶X 射线衍射法表征.

关键词： 芳醛; 4-羟基-6-甲基-2-吡喃酮; 1,3-环己二酮; 二氧杂蒽; 晶体结构

本文引用格式

游新奎 , 林志兰 , 张雪利 , 高原 . 3-甲基-9-芳基-1,8-二氧代-2,10-二氧杂蒽衍生物的合成[J]. 有机化学, 2012 , 32(01) : 156 -159 . DOI: 10.6023/cjoc1104071

Abstract

A series of 9-aryl-3-methyl-1,8-dioxo-2,10-dioxanthens were synthesized by the reaction of aromatic aldehydes, 4-hydroxyl-6-methyl-2-pyranone and 1,3-cyclohexadione in glycol. The structures of the products were determined by IR, NMR and X-ray diffraction analysis.

Key words： aromatic aldehyde; 4-hydroxyl-6-methyl-2-pyranone; 1,3-cyclohexadione; dioxanthen; crystal stucture

参考文献

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