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2012 , Vol. 32 >Issue 02: 393 - 396

DOI: https://doi.org/10.6023/cjoc1012142

研究简报

竹炭磺酸催化一锅三组分合成α-氨基膦酸酯

  • 周晓红 ,
  • 徐琼 ,
  • 梁静 ,
  • 伏再辉 ,
  • 尹笃林
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  • 湖南师范大学精细催化合成研究所 资源精细化及先进材料湖南省高校重点实验室石化新材料湖南省工程实验室 长沙 410081

收稿日期: 2011-02-14

  修回日期: 2011-07-14

  网络出版日期: 2012-03-09

基金资助

国家自然科学基金(No. 20572021)和湖南省自然科学基金(No. 09JJ5006)资助项目.

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Synthesis of α-Amino Phosphonates from One-Pot Three- Component Condensation Catalyzed by Bamboo Char Sulfonic Acid

  • ZHOU Xiao-Hong ,
  • XU Qiong ,
  • LIANG Jing ,
  • FU Zai-Hui ,
  • YIN Du-Lin
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  • Key Laboratory of Resource Fine-Processing and Advanced Materials, Universities of Hunan Province, Hunan Engineering Laboratory for Petrochemical New Materials, Institute of Fine Catalysis and Synthesis, Hunan Normal University, Changsha 410081

Received date: 2011-02-14

  Revised date: 2011-07-14

  Online published: 2012-03-09

Supported by

Project supported by the National Natural Science Foundation of China (No. 20572021), and the Natural Science Foundation of Hunan Province (No. 09JJ5006).

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摘要

以新鲜竹材为原料, 经炭化和磺化制得的竹炭磺酸催化各种芳醛、芳胺和亚膦酸二乙酯一锅三组分合成α-氨基膦酸酯. 结果表明: 该固体酸具有催化性能好、操作简便、来源广泛和可重复利用等优点.

关键词： 竹炭磺酸; 非均相催化; 一锅法; α-氨基膦酸酯

本文引用格式

周晓红 , 徐琼 , 梁静 , 伏再辉 , 尹笃林 . 竹炭磺酸催化一锅三组分合成α-氨基膦酸酯[J]. 有机化学, 2012 , 32(02) : 393 -396 . DOI: 10.6023/cjoc1012142

Abstract

By using fresh bamboo condensation raw material, bamboo char sulfonic acid was obtained via sulfuric acid charring and sulfonation, which catalyzed the one-pot three-component synthesis of α-amino phosphonates by condensation of various aromatic aldehydes with aromatic amines and diethyl phosphite. Experimental results have shown that bamboo char sulfonic acids have advantages of high activity, simplicity of operation, wide range of sources and easy recycle.

Key words： bamboo char sulfonic acid; heterogeneous catalysis; one-pot reaction; α-amino phosphonates

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