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2012 , Vol. 32 >Issue 06: 1121 - 1125

DOI: https://doi.org/10.6023/cjoc1112141

研究简报

Keggin 结构型硅钨酸催化β-萘酚与醛的缩合反应

  • 韩波 ,
  • 刘飞飞 ,
  • 张玉琦 ,
  • 王俏 ,
  • 马荣萱 ,
  • 郭宏
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  • 延安大学化学与化工学院 延安 716000

收稿日期: 2011-12-14

  修回日期: 2012-02-04

  网络出版日期: 2012-02-27

基金资助

陕西省教育厅专项科研基金(No. 11JK0563)资助项目.

收起

Condensation Reactions between Aldehydes and β-Naphthol Catalyzed by Silicotungstic Acid

  • Han Bo ,
  • Liu Feifei ,
  • Zhang Yuqi ,
  • Wang Qiao ,
  • Ma Rongxuan Guo Hong
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  • College of Chemistry and Chemical Engineering, Yan'an University, Yan'an 716000

Received date: 2011-12-14

  Revised date: 2012-02-04

  Online published: 2012-02-27

Supported by

Project supported by the Natural Science Foundation of Shaanxi Education Deparment (Grant No. 11JK0563).

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摘要

以keggin 型硅钨酸为催化剂, β-萘酚、醛为原料, 在乙醇和无溶剂两种体系中, 分别合成了1,1'-烷基(芳基)二-2-萘酚和14-烷基(芳基)-14H-二苯并[a,j]氧杂蒽两类化合物. 该方法不仅反应时间短, 产率高, 后处理简单易分离, 而且催化剂价廉易得, 对环境友好.

关键词： 氧杂蒽; 醛; β-萘酚; 硅钨酸

本文引用格式

韩波 , 刘飞飞 , 张玉琦 , 王俏 , 马荣萱 , 郭宏 . Keggin 结构型硅钨酸催化β-萘酚与醛的缩合反应[J]. 有机化学, 2012 , 32(06) : 1121 -1125 . DOI: 10.6023/cjoc1112141

Abstract

Under ethanol and solvent-free conditions, 1,1'-alkyl(aryl)-bis(naphthalen-2-ol) and 14-alkyl(aryl)-14H-dibeno[a,j]xanthenes were successfully synthesized from β-naphthol and aldehydes by using silicotungstic acid with keggin structure as the catalyst. The reaction catalyzed by silicotungstic acid has the advantage of short reaction time, high yield, simple workup procedures and easy isolation. The catalyst was inexpensive and environmentally friendly.

Key words： xanthene; aldehyde; β-naphthol; silicotungstic acid

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