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2012 >Issue 03: 627 - 631

DOI: https://doi.org/10.6023/cjoc1107202

研究简报

3-戊烯腈在零价镍催化体系中的平衡反应

  • 董建勋 ,
  • 石玉坤 ,
  • 胡晓静 ,
  • 冯晓燕 ,
  • 宋娟娟 ,
  • 丁真贞
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  • a 南开大学化学系 天津 300071;
    b 中国平煤神马能源化工集团尼龙化工公司 平顶山 467013

收稿日期: 2011-07-20

  修回日期: 2011-10-25

  网络出版日期: 2012-03-24

基金资助

国家自然科学基金(No. 21071086)资助项目.

收起

Nickel(0)-Catalyzed Equilibrium Reaction of 3-Pentenenitrile

  • Dong Jianxun ,
  • Shi Yukun ,
  • Hu Xiaojing ,
  • Feng Xiaoyan ,
  • Song Juanjuan ,
  • Ding Zhenzhen
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  • a College of Chemistry, Nankai University, Tianjin 300071;
    b China Pingmei Shenma Energy and Chemical Group Nylon Chemical Company, Pingdingshan 467013

Received date: 2011-07-20

  Revised date: 2011-10-25

  Online published: 2012-03-24

Supported by

Project supported by the National Natural Science Foundation of China (No. 21071086).

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摘要

在探索3-戊烯腈氢氰化合成己二腈反应的机理过程中, 发现3-戊烯腈在零价镍体系中可能同时存在多个平衡反应, 在不外加氰化氢条件下, 3-戊烯腈可以生成甲基戊二腈和己二腈. 采用零价镍、膦配体和无水ZnCl2 组成的催化体系研究了该反应过程, 考察了反应温度和配体的影响, 并采用原位红外对反应进行监测, 提出了可能的反应机理.

关键词： 零价镍; 3-戊烯腈; 2-甲基戊二腈; 己二腈; 反应平衡

本文引用格式

董建勋 , 石玉坤 , 胡晓静 , 冯晓燕 , 宋娟娟 , 丁真贞 . 3-戊烯腈在零价镍催化体系中的平衡反应[J]. 有机化学, 2012 , (03) : 627 -631 . DOI: 10.6023/cjoc1107202

Abstract

The equilibrium reaction of 3-pentenenitrile was carried out in the system containing Ni(0), P-ligand and anhydrous ZnCl2. The equilibrium state of 3-pentenenitrile was affected by factors such as reaction temperatures and different ligands, which were investigated. The FTIR-ATR was used to monitor the reaction process of 3-pentenenitrile turning into 2-methylglutaronitrile and adiponitrile in absence of HCN and the possible reaction mechanism was proposed.

Key words： zero-valent nickel; 3-pentenenitrile; 2-methylglutaronitrile; adiponitrile; reaction equilibrium

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