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2012 , Vol. 32 >Issue 04: 661 - 666

DOI: https://doi.org/10.6023/cjoc1104113

综述与进展

β,β-二氟乙烯基化合物制备方法研究进展

  • 刘运 ,
  • 邓萌萌 ,
  • 张智勇 ,
  • 丁肖华 ,
  • 戴志群 ,
  • 关金涛
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  • 武汉工业学院化学与环境工程学院 武汉 430023

收稿日期: 2011-04-11

  修回日期: 2011-09-19

  网络出版日期: 2012-04-24

基金资助

国家自然科学基金(No. 60736)、湖北省自然科学基金(No. 2007ABA279)、湖北省教育厅科技基金(No. Z0091801)、武汉工业学院研究生教育创新计划(No. 09cx19)资助项目.

收起

Progress in Preparation of β,β-Difluorovinyl Compounds

  • Liu Yun ,
  • Deng Mengmeng ,
  • Zhang Zhiyong ,
  • Ding Xiaohua ,
  • Dai Zhiqun ,
  • Guan Jintao
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  • Department of Chemistry and Environmental Engineering, Wuhan Polytechnic University, Wuhan 430023

Received date: 2011-04-11

  Revised date: 2011-09-19

  Online published: 2012-04-24

Supported by

Project supported by the National Natural Science Foundation of China (No. 60736), the Natural Science Foundation of Hubei Province of China (No. 2007ABA279), the Scientific Research Fund of Hubei Provincial Education Department (No. Z0091801), and the Educational and Innovative Foundation for the Graduate Students of Wuhan Polytechnic University (No. 09cx19).

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摘要

近年来, 随着β,β-二氟乙烯基类化合物的广泛应用, 其合成方法的研究也越来越多. 详细介绍了卤代二氟醋酸盐、卤代二氟甲烷、双膦酸盐、有金属参与、双三氟甲基汞和二异丙基胺基锂和二氟甲基芳环砜等法制备β,β-二氟乙烯的研究进展, 同时对其反应机理作了相应阐述.

关键词： 二氟乙烯; Wittig 反应; 磷叶立德

本文引用格式

刘运 , 邓萌萌 , 张智勇 , 丁肖华 , 戴志群 , 关金涛 . β,β-二氟乙烯基化合物制备方法研究进展[J]. 有机化学, 2012 , 32(04) : 661 -666 . DOI: 10.6023/cjoc1104113

Abstract

Numerous methods for the preparation of β,β-difluorovinyl compounds have been reported with the widely application of difluoroethenes recently. In this paper, an overview on the progress of synthetic methods of β,β-difluorovinyl compounds, based on halodifluroacetate, halodifluoromethane, bi-sphosphonium salts, metal-assisted, double-trifluoromethyl mercury, LDA and difluormethyl aromatic sulfone, has been introduced. And the relevant reaction mechanisms are also proposed and explained.

Key words： difluoroethylene; Wittig reaction; phosphorus ylide

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