莪术醇在Woodward-Prévost反应条件下的产物研究
Some Products of Curcumol under the Woodward-Pr関ost Conditions
Received date: 2012-04-05
Revised date: 2012-05-28
Online published: 2012-06-04
莪术醇分子中含有末端双键, 将其置于Woodward-Prévost反应条件下, 并未获得α-碘代乙酸酯、双乙酸酯、羟基乙酸酯等衍生物, 而得到几个不同产物A～C. 产物A～C通过质谱、核磁共振和X衍射分析确证结构, 并对产物产生的可能过程进行了讨论.
关键词： 莪术醇; 衍生物; Woodward-Prévost反应
郭平 , 刘剑敏 , 叶发青 , 李校堃 , 姚其正 . 莪术醇在Woodward-Prévost反应条件下的产物研究[J]. 有机化学, 2012 , 32(10) : 2003 -2006 . DOI: 10.6023/cjoc201204007
Curcumol reacts under the Woodward-Prévost conditions providing not usual products but several unexpected derivatives A～C. The structures of compounds A～C were determined by MS, NMR and X-ray diffraction analysis. A plausible mechanism involved in their formation was discussed.
Key words： curcumol; derivatives; Woodward-Pr関ost reaction
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