研究论文

水相中磺化杯[6]芳烃催化醇的胺基化反应研究

  • 晏利琴 ,
  • 张平 ,
  • 冯寅寅 ,
  • 商永嘉
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  • 安徽师范大学化学与材料科学学院 芜湖 241000

收稿日期: 2012-06-19

  修回日期: 2012-07-20

  网络出版日期: 2012-07-29

基金资助

国家自然科学基金(No. 21172001)资助项目.

Study on the Dehydrate Amination of Alcohols in Water Using Sulfonic Calix[6]resorcinarene

  • Yan Liqin ,
  • Zhang Ping ,
  • Feng Yinyin ,
  • Shang Yongjia
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  • College of Chemistry and Materials Science, Anhui Normal University, Wuhu 230061

Received date: 2012-06-19

  Revised date: 2012-07-20

  Online published: 2012-07-29

Supported by

Project supported by the National Natural Science Foundation of China (No. 21172001).

摘要

研究了水相中磺化杯[6]芳烃在酸性条件下催化合成含C—N键类化合物的反应, 高效的合成了一系列产物, 其结构经1H NMR,13C NMR表征. 并探究了时间、温度对反应的影响和催化剂的循环使用情况. 研究表明水溶性的磺化杯[6]芳烃具有很好的相转移催化性能和多次重复使用性.

本文引用格式

晏利琴 , 张平 , 冯寅寅 , 商永嘉 . 水相中磺化杯[6]芳烃催化醇的胺基化反应研究[J]. 有机化学, 2012 , 32(11) : 2095 -2098 . DOI: 10.6023/cjoc201206020

Abstract

The dehydrate amination of alcohols was investigated in water using sulfonic calix[6]resorcinarene and acid. A series of aminations were synthesized in high yields. The structures were characterized by 1H NMR and 13C NMR speetra. Water-soluble sulfonic calix[6]resorcinarene could be reused times and without a loss of catalytic efficiency.

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