研究论文

钯/碳高效绿色催化Suzuki交叉偶联反应

  • 初文毅 ,
  • 王熳 ,
  • 李新民 ,
  • 侯艳君 ,
  • 孙志忠
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  • a 黑龙江大学化学化工与材料学院 哈尔滨 150080;
    b 黑龙江省普通高等学校高效转化的化工过程与技术重点实验室 哈尔滨 150080

收稿日期: 2012-06-30

  修回日期: 2012-07-18

  网络出版日期: 2012-07-14

基金资助

黑龙江省教育厅科技(No.12511383)和哈尔滨市科技局科技创新人才研究专项基金(No.RC2012XK001005)资助项目

Pd/C-Catalyzed Highly Efficient and Green Suzuki Cross-Coupling Reaction

  • Wang Man ,
  • Li Xinmin ,
  • Hou Yanjun ,
  • Sun Zhizhong
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  • a School of Chemistry and Materials Science, Heilongjiang University, Harbin 150080;
    b Key Laboratory of Chemical Engineering Process & Technology for High-efficiency Conversion, College of Heilongjiang Province, Harbin 150080

Received date: 2012-06-30

  Revised date: 2012-07-18

  Online published: 2012-07-14

Supported by

Project supported by the Research Project of Education Department of Heilongjiang Province of China (No.12511383) and the Research Special Funds for Innovation Talent of Harbin of China (No.RC2012XK001005)

摘要

开发了一个以钯/碳为催化剂高效绿色催化Suzuki反应制备联苯类化合物的新方法.该体系以环境友好的聚乙二醇400的水溶液为反应溶剂,加入离子液体1-甲基-3-丁基咪唑双三氟甲磺酰亚胺盐,可高效催化溴代芳烃与芳基硼酸的Suzuki交叉偶联反应,并且催化剂可以循环利用4次而催化效率没有明显降低.

本文引用格式

初文毅 , 王熳 , 李新民 , 侯艳君 , 孙志忠 . 钯/碳高效绿色催化Suzuki交叉偶联反应[J]. 有机化学, 2012 , 32(9) : 1666 -1672 . DOI: 10.6023/cjoc201206029

Abstract

An efficient protocol for the Suzuki reaction catalyzed by Pd/C has been developed in a green sovent. This method is able to prepare a variety of biaryls in high yields. In the presence of 1-butyl-3-methylimidazolium bis[(trifluoro-methyl)sulfonyl]imide, the cross-coupling reaction of aryl bromides with arylboronic acids proceed smoothly in PEG400 aqueous at 45℃. The catalyst could be recycled four times without loss of activity.

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