新颖的银(I)催化磺酰氯与芳香端炔的反应
收稿日期: 2012-04-11
修回日期: 2012-06-07
网络出版日期: 2012-06-19
A Novel Silver(I)-Catalyzed Reaction of Terminal Arylacetylenes with Sulfonyl Chlorides
Received date: 2012-04-11
Revised date: 2012-06-07
Online published: 2012-06-19
邓桂胜 , 孙腾飞 , 周佳 . 新颖的银(I)催化磺酰氯与芳香端炔的反应[J]. 有机化学, 2012 , 32(10) : 1872 -1879 . DOI: 10.6023/cjoc201204011
A novel reaction of terminal arylacetylenes with sulfonyl chlorides was performed in the presence of a silver(I) catalyst. Vinyl sulfones were obtained in 47%～72% yields. A free radical mechanism for the catalytic cycle has been proposed to account for the formation of products and the stereochemical outcome of vinyl sulfones.
Key words： alkynes; sulfonyl chlorides; vinyl sulfones; silver salt; alkynyl silver
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