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2013 , Vol. 33 >Issue 02: 359 - 364

DOI: https://doi.org/10.6023/cjoc201209016

研究论文

实时直接分析质谱法快速鉴别天然驱蚊产品中的人工添加剂

  • 祁婉舒 ,
  • 张立 ,
  • 郭寅龙
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  • 中国科学院上海有机化学研究所 上海 200032

收稿日期: 2012-09-11

  修回日期: 2012-10-12

  网络出版日期: 2012-10-16

基金资助

国家自然科学基金(Nos. 21202192, 21275155)及国家科技部创新工作方法(Nos. 2011IM030200, 2011IM030400, 2011IM030700)资助项目.

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Rapid Identification of Synthetic Compounds in Natural Repellent Products by Direct Analysis in Real Time Mass Spectrometry

  • Qi Wanshu ,
  • Zhang Li ,
  • Guo Yinlong
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  • Shanghai Mass Spectrometry Center, Shanghai Institute of Organic Chemistry, Chinese Academy of Science, Shanghai 200032

Received date: 2012-09-11

  Revised date: 2012-10-12

  Online published: 2012-10-16

Supported by

Project supported by the National Natural Science Foundation of China (Nos. 21202192, 21275155) and the Innovation Method Fund of China (Nos. 2011IM030200, 2011IM030400, 2011IM030700).

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摘要

采用DART-MS(实时直接分析质谱法)建立了一种简单快速测定人工合成驱蚊化合物如DEET(避蚊胺)、BAAPE(驱蚊酯)等的方法. 在常温常压下, 无需对天然驱蚊产品进行任何预处理, 通过比对标准品的质谱信号离子, 即可快速鉴别出天然驱蚊产品中的人工添加剂. 该方法大大缩短了分析时间, 并且具有原位、准确且高通量的优点.

关键词： 实时直接分析; 质谱; 昆虫驱避剂; 快速鉴别

本文引用格式

祁婉舒 , 张立 , 郭寅龙 . 实时直接分析质谱法快速鉴别天然驱蚊产品中的人工添加剂[J]. 有机化学, 2013 , 33(02) : 359 -364 . DOI: 10.6023/cjoc201209016

Abstract

A rapid and simple method for identification of the synthetic repellent compounds such as DEET and BAAPE has been developed based on direct analysis in real time mass spectrometry (DART-MS). Through this method, the synthetic compounds in natural repellent products can be identified by comparison of characteristic mass spectrometric signals. Without any sample pretreatment, all of these were achieved at room temperature and atmospheric pressure. This method greatly reduces the analysis time, with the advantages of accurate, high throughput and in situ.

Key words： direct analysis in real time (DART); mass spectrometry; insect repellent; rapid identification

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