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2013 , Vol. 33 >Issue 02: 339 - 342

DOI: https://doi.org/10.6023/cjoc201208008

研究论文

溴化二甲基溴化硫(BDMS)催化的2-芳基苯并噻唑的合成

  • 张丽君 ,
  • 刘巨艳 ,
  • 王英
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  • 天津师范大学化学学院/天津市功能分子结构与性能重点实验室/无机-有机杂化功能材料化学省部共建 教育部重点实验室 天津 300387

收稿日期: 2012-08-11

  修回日期: 2012-10-29

  网络出版日期: 2012-10-30

基金资助

天津市自然科学基金(Nos. 12JCZDJC34300, 11JCYBJC03600);青年科学基金(No. 21001080)资助项目.

收起

Bromodimethylsulfonium Bromide (BDMS)-Catalyzed Synthesis of 2-Arylbenzothiazoles

  • Zhang Lijun ,
  • Liu Juyan ,
  • Wang Ying
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  • Tianjin Key Laboratory of Structure and Performance for Functional Molecule, Key Laboratory of Inorganic-Organic Hybrid Functional Material Chemistry, Ministry of Education, College of Chemistry, Tianjin Normal University, Tianjin 300387

Received date: 2012-08-11

  Revised date: 2012-10-29

  Online published: 2012-10-30

Supported by

Project supported by the Natural Science Foundation of Tianjin City (Nos. 12JCZDJC34300, 11JCYBJC03600), the Young Scientist Fund (No. 21001080).

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摘要

室温下, 以溴化二甲基溴化硫(BDMS)为催化剂, 以芳香醛和2-氨基苯硫酚为原料, 在1～30 min的反应时间内, 能够较高效率地合成2-芳基苯并噻唑类化合物. 此合成方法具有以下显著特点: 操作简便, 催化剂易得, 产率高, 反应时间短.

关键词： 2-芳基苯并噻唑; 溴化二甲基溴化硫(BDMS); 无溶剂

本文引用格式

张丽君 , 刘巨艳 , 王英 . 溴化二甲基溴化硫(BDMS)催化的2-芳基苯并噻唑的合成[J]. 有机化学, 2013 , 33(02) : 339 -342 . DOI: 10.6023/cjoc201208008

Abstract

Bromodimethylsulfonium bromide (BDMS)-catalyzed condensation between aromatic aldehydes and 2-aminothiophenol is reported to access 2-arylbenzothiazoles at room temperature in moderate to high yields within 1～30 min. The salient features of this method are the simplicity of the procedure, the ready accessibility of the catalyst, and higher yields in relatively short reaction times.

Key words： 2-arylbenzothiazoles; bromodimethylsulfonium bromide (BDMS); solvent-free

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