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2013 , Vol. 33 >Issue 04: 771 - 779

DOI: https://doi.org/10.6023/cjoc201211022

综述与进展

锕系端基亚胺金属有机化合物研究进展

  • 任文山 ,
  • 赵宁 ,
  • 陈亮 ,
  • 自国甫
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  • a 北京师范大学化学学院 北京 100875;
    b 西南大学化学化工学院 重庆 400715

收稿日期: 2012-11-12

  修回日期: 2012-12-07

  网络出版日期: 2012-12-07

基金资助

国家自然科学基金(Nos. 20972018, 21074013, 21172022)和教育部新世纪优秀人才支持计划(No. NCET-10-0253)资助项目.

收起

Progress in Terminal-Imido Organoactinide Complexes

  • Ren Wenshan ,
  • Zhao Ning ,
  • Chen Liang ,
  • Zi Guofu
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  • a College of Chemistry, Beijing Normal University, Beijing 100875;
    b College of Chemistry and Chemical Engineering, Southwest University, Chongqing 400715

Received date: 2012-11-12

  Revised date: 2012-12-07

  Online published: 2012-12-07

Supported by

Project supported by the National Natural Science Foundation of China (Nos. 20972018, 21074013, 21172022) and the Program for New Century Excellent Talents in University (No. NCET-10-0253).

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摘要

在过去的30多年中, 锕系端基亚胺金属有机化合物因其具有独特的结构特征以及在基团转换与催化方面的潜在应用而受到人们的广泛研究, 并取得了一些很好的成果. 目前, 锕系端基亚胺金属有机化合物已成为金属有机化学领域中一个引人注目的研究热点. 这篇综述主要介绍了锕系端基亚胺金属有机化合物在合成及反应性能方面的研究进展.

本文引用格式

任文山 , 赵宁 , 陈亮 , 自国甫 . 锕系端基亚胺金属有机化合物研究进展[J]. 有机化学, 2013 , 33(04) : 771 -779 . DOI: 10.6023/cjoc201211022

Abstract

The terminal-imido organoactinide complexes have received widespread attention over the past three decades due to their unique structural properties and their potential applications in group transfer and catalysis. At present, studies on terminal-imido organoactinide complexes have been regarded as one of the most remarkable fields in organometallic chemistry. This review focuses on the preparation and reactivity study of terminal-imido organoactinide complexes.

Key words： imido complex; organoactinide; preparation; reactivity

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