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2013 , Vol. 33 >Issue 04: 687 - 692

DOI: https://doi.org/10.6023/cjoc201301023

研究专题

过渡金属催化的对甲苯磺酰腙的偶联反应

  • 刘振兴 ,
  • 张艳 ,
  • 王剑波
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  • 北京大学化学与分子工程学院 生物有机与分子工程教育部重点实验室 北京分子科学国家实验室 北京 100871

收稿日期: 2013-01-11

  修回日期: 2013-01-31

  网络出版日期: 2013-02-01

基金资助

科技部973计划(No. 2009CB825300)和国家自然科学基金委(No. 21272010)资助项目.

收起

Transition-Metal-Catalyzed Cross-Coupling Reaction with N-Tosylhydrazones

  • Liu Zhenxing ,
  • Zhang Yan ,
  • Wang Jianbo
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  • Beijing National Laboratory of Molecular Sciences (BNLMS) and Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry, Peking University, Beijing 100871

Received date: 2013-01-11

  Revised date: 2013-01-31

  Online published: 2013-02-01

Supported by

Project supported by the National Basic Research Program of China (973 Program, No. 2009CB825300) and the National Natural Science Foundation of China (No. 21272010).

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摘要

对我们研究小组近几年在对甲苯磺酰腙在有机合成中的应用进行综述. 重点介绍了其在过渡金属催化的偶联反应中的应用, 同时对腙参与的不含过渡金属的反应也做了简单讨论.

关键词： 对甲苯磺酰腙; 交叉偶联; 金属卡宾; 有机合成

本文引用格式

刘振兴 , 张艳 , 王剑波 . 过渡金属催化的对甲苯磺酰腙的偶联反应[J]. 有机化学, 2013 , 33(04) : 687 -692 . DOI: 10.6023/cjoc201301023

Abstract

Our recent progress in the development of N-tosylhydrazones involved reactions and their applications in organic synthesis are summarized in this account. Among these reactions, transition-metal catalyzed cross-coupling reactions are highlighted, while transition-metal free reactions are also discussed.

Key words： N-tosylhydrazones; cross-coupling; metal carbene; organic synthesis

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