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2013 , Vol. 33 >Issue 04: 749 - 759

DOI: https://doi.org/10.6023/cjoc201301032

综述与进展

手性双金属催化剂及其在不对称催化反应中的应用

  • 李昆 ,
  • 杨国强 ,
  • 刘媛媛 ,
  • 张万斌
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  • 上海交通大学化学化工学院 上海 200240

收稿日期: 2013-01-14

  修回日期: 2013-02-14

  网络出版日期: 2013-02-22

基金资助

国家自然科学基金(Nos. 20972095, 21172143, 21232004)和上海市科学技术委员会(No. 09JC1407800)资助项目.

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Chiral Polymetallic Catalysts and Their Applications in Asymmetric Catalysis

  • Li Kun ,
  • Yang Guoqiang ,
  • Liu Yuanyuan ,
  • Zhang Wanbin
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  • School of Chemistry and Chemical Engineering, Shanghai Jiaotong University, Shanghai 200240

Received date: 2013-01-14

  Revised date: 2013-02-14

  Online published: 2013-02-22

Supported by

Project supported by the National Natural Science Foundation of China (Nos. 20972095, 21172143 and 21232004) and the Science and Technology Commission of Shanghai Municipality (No. 09JC1407800).

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摘要

多金属催化过程是生命体实现新陈代谢的主要方式之一, 在自然界广泛存在. 多金属催化剂相比于单金属催化剂, 具有更加高的反应活性和对映选择性, 近年来其设计与应用已经成为有机化学的研究热点之一. 综述了近年来不同种类的具有代表性的双金属催化剂的研究进展, 包括双杂金属和双核同金属, 介绍了双金属催化剂的反应类型、反应机理以及发展现状, 提出了今后的研究重点与发展趋势.

关键词： 不对称催化; 多金属; 双核同金属催化剂; 双杂金属催化剂

本文引用格式

李昆 , 杨国强 , 刘媛媛 , 张万斌 . 手性双金属催化剂及其在不对称催化反应中的应用[J]. 有机化学, 2013 , 33(04) : 749 -759 . DOI: 10.6023/cjoc201301032

Abstract

Polymetallic catalytic process is the main metabolic way of life, which is widely observed in nature. Compared to the mono-metal catalysts, the designs and applications of polymetallic catalysts with high reactivity and enantioselectivity have been a hot research topic in organic chemistry recently. This review covers the recent research process on representative types of bimetallic catalysts, including hetero-bimetallic catalysts and dinuclear homometal catalysts, their reaction mechanisms and developments. Moreover, potentially development of this area is also discussed.

Key words： asymmetric catalysis; polymetallic; dinuclear homometal catalyst; hetero-bimetallic catalyst

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