吲哚与硝基烯的Friedel-Crafts反应的研究进展
收稿日期: 2013-01-21
修回日期: 2013-03-18
网络出版日期: 2013-04-07
基金资助
国家自然科学基金(Nos. 21262034, 20962018, 20862015, 20562011)资助项目
Research Progress in Friedel-Crafts Reaction of Indoles and Nitroalkenes
Received date: 2013-01-21
Revised date: 2013-03-18
Online published: 2013-04-07
Supported by
Project supported by the National Natural Science Foundation of China (Nos. 21262034, 20962018, 20862015, 20562011)
吲哚作为核心结构广泛存在于生物碱和药物中, 吲哚衍生物在生物体的生理活动中起着重要的作用, 其中吲哚和硝基烯的Friedel-Crafts是生成吲哚衍生物的重要方法. 按照反应中催化剂种类的不同分为: (1)无催化剂, (2)离子液体催化剂, (3)金属盐催化剂, (4)配合物催化剂, (5) Brønsted酸催化剂, (6)有机小分子催化剂, (7)其他类型催化剂. 对吲哚与硝基烯的Friedel-Crafts反应的情况进行了综述.
关键词： Friedel-Crafts反应; 吲哚; 硝基烯; 催化剂
王春超 , 谢绍雷 , 解正峰 . 吲哚与硝基烯的Friedel-Crafts反应的研究进展[J]. 有机化学, 2013 , 33(9) : 1919 -1931 . DOI: 10.6023/cjoc201301051
Indoles, as the core structure, exist widely in many alkaloid natural products and pharmaceuticals. The derivatives of indole play an important role in organism physiological activities. The Friedel-Crafts reaction of indoles and nitroalkenes is an important method to generate indole derivatives. According to the kinds of the catalyst in the reaction, the Friedel-Crafts reactions of indoles and nitroalkenes were summarized in this paper as follows: (1) catalyst-free, (2) ionic liquid catalyst, (3) metal salt catalyst, (4) coordination compound catalyst, (5) Brønsted acid catalyst, (6) small molecular organic catalyst, (7) other catalysts.
Key words： Friedel-Crafts reaction; indole; nitroolefin; catalyst
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