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2013 , Vol. 33 >Issue 06: 1337 - 1339

DOI: https://doi.org/10.6023/cjoc201304016

研究简报

双花千里光中一个新的呋喃骈雅槛蓝烷型倍半萜

  • 黄帅 ,
  • 张吉发 ,
  • 黄晶 ,
  • 周先礼 ,
  • 单连海 ,
  • 王萃娟 ,
  • 翁杰
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  • a 西南交通大学生命科学与工程学院 成都 610031;
    b 西南交通大学材料先进技术教育部重点实验室 成都 610031

收稿日期: 2013-04-15

  修回日期: 2013-05-13

  网络出版日期: 2013-05-15

基金资助

国家自然科学基金(No.31171695 );四川省科技支撑计划(No.2013SZ0083);中央高校基本科研业务费专项(Nos.SWJTU2010ZT09, SWJTU12CX048)资助项目.

收起

New Furanoeremophilanen Derivative from Senecio dianthus

  • Huang Shuai ,
  • Zhang Jifa ,
  • Huang Jing ,
  • Zhou Xianli ,
  • Shan Lianhai ,
  • Wang Cuijuan ,
  • Weng Jie
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  • a School of Life Science and Engineering, Southwest Jiaotong University, Chengdu 610031;
    b Key Laboratory of Advanced Technologies of Materials MOE, Southwest Jiaotong University, Chengdu 610031

Received date: 2013-04-15

  Revised date: 2013-05-13

  Online published: 2013-05-15

Supported by

Project supported by the National Natural Science Foundation of China (No.31171695), the Science and Technology Support Programs of Sichuan Province (No.2013SZ0083), and the Fundamental Research Funds for Central Universities (Nos.SWJTU2010ZT09, SWJTU12CX048).

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摘要

从藏药双花千里光中分离得到2个倍半萜类化合物, 经过HR-ESIMS, 1D和2D NMR等光谱技术, 将上述化合物鉴定为6-oxo-9α-angloyloxy-10bH-furanoeremophilane (1)和spiroeuryolide (2).化合物1为新的呋喃骈雅槛蓝烷倍半萜.同时, 对文献报告中化合物2的13C NMR数据进行了纠正.

关键词： 菊科; 双花千里光; 呋喃骈雅槛蓝烷倍半萜; spiroeuryolide

本文引用格式

黄帅 , 张吉发 , 黄晶 , 周先礼 , 单连海 , 王萃娟 , 翁杰 . 双花千里光中一个新的呋喃骈雅槛蓝烷型倍半萜[J]. 有机化学, 2013 , 33(06) : 1337 -1339 . DOI: 10.6023/cjoc201304016

Abstract

A new furanoeremophilanen derivative, 6-oxo-9α-angloyloxy-10bH-furanoeremophilane (1) was isolated from the aerial parts of Senecio dianthus, together with a known compound, spiroeuryolide 2.Their structures were elucidated on the basis of extensive spectroscopic analysis, including HR-ESI-MS, 1D and 2D NMR experiments.Compound 2 was isolated from the plant for the first time.Complete 1H NMR and 13C NMR spectral assignments of 2 were leading to revision of some 13C NMR assignments previously made for this compound.

Key words： asteraceae; Senecio dianthus Franch; furanoeremophilane derivative; spiroeuryolide

参考文献

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[5] Wang, Q.; Mu, Q.; Shibano, M.; Morris-Natschke, S.L.; Lee, K.H.; Chen, D.F.J.Nat.Prod 2007, 70, 1259.
[6] Bohlmann, F.; Forster, H.J.; Justus, C.H.Liebigs Ann.Chem.1976, 1487.
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