芳基氟硼酸盐同芳香胺“一锅法”Suzuki-Miyaura反应
收稿日期: 2013-06-07
修回日期: 2013-07-04
网络出版日期: 2013-07-10
基金资助
国家自然科学基金（No. 21202102）、浙江省科技厅（No. 2012R10014-15）和绍兴市科技计划（No. 2013014017）资助项目.
“One-Pot” Suzuki-Miyaura Reaction with Aryltrifluoroborate Salts from Aromatic Amines
Received date: 2013-06-07
Revised date: 2013-07-04
Online published: 2013-07-10
Supported by
Project supported by the National Natural Science Foundation of China (No. 21202102), the Science Technology Department of Zhejiang Province (No. 2012R10014-15) and the Scienece Technology Project of Shaoxing City (No. 2013014017).
韦珊红 , 王晨 , 王建伟 , 程凯 . 芳基氟硼酸盐同芳香胺“一锅法”Suzuki-Miyaura反应[J]. 有机化学, 2013 , 33(11) : 2402 -2406 . DOI: 10.6023/cjoc201306008
Palladium-catalyzed "one-pot" Suzuki-Miyaura reactions of various aromatic amines with aryltrifluoroborate salts have been achieved in good yields under simple aerobic conditions in water without heating. The reported cross-coupling reac-tions are tolerant to the common functional groups regardless of electron-withdrawing or electron donating, making these transformations as attractive alternatives to the traditional cross-coupling approaches. Theoretical calculation shows that the coordination of tert-butoxide can lower the transition state energy by 50 kJ/mol for the transmetalation step.
Key words： cross-coupling; green chemistry; diazo compounds
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