微波辐照下烯烃和重氮化合物无催化剂的环丙烷化反应
收稿日期: 2013-07-19
修回日期: 2013-08-19
网络出版日期: 2013-08-29
基金资助
国家自然科学基金(Nos. 21074097，21274112)、光电化学材料与器件教育部重点实验室开放项目基金(No. JDGD-2012-07)资助项目.
Catalyst-Free Cyclopropanation of Alkenes with Diazocompounds under Microwave Irradiation
Received date: 2013-07-19
Revised date: 2013-08-19
Online published: 2013-08-29
Supported by
Project supported by the National Natural Science Foundation of China (Nos. 21074097, 21274112), and the Found of Key Laboratory of Optoelectronic Chemical Materials and Devices of Ministry of Educatio (No. JDGD-2012-07).
蔡少君 , 肖龙强 , 廖立琼 , 刘立建 . 微波辐照下烯烃和重氮化合物无催化剂的环丙烷化反应[J]. 有机化学, 2013 , 33(12) : 2602 -2606 . DOI: 10.6023/cjoc201307030
Cyclopropane derivatives were prepared by the reaction of diazocompounds and alkene without catalyst under microwave irradiation, which demonstrated that it is an efficient method in organic chemistry. Compared with traditional metal catalyzed cyclopropane, this method is convenient and less harmful to environment. A second-order process was involved in the cyclopropanation as shown by the kinetic study.
Key words： cyclopropanation; diazocompound; microwave; kinetic study; green chemistry
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