多齿络合法分离锂同位素的冠醚化学
收稿日期: 2013-07-19
修回日期: 2013-10-11
网络出版日期: 2013-10-16
基金资助
中国科学院战略性先导科技专项（No.XDA01020304）资助项目.
Crown Ether Chemistry of Polydentate Complexing for Lithium Isotope Separation
Received date: 2013-07-19
Revised date: 2013-10-11
Online published: 2013-10-16
Supported by
Project supported by the "Stategic Priority Research Program" of the Chinese Academy of Science (No. XDA01020304).
刘华 , 黄祚刚 , 文珂 , 姜标 . 多齿络合法分离锂同位素的冠醚化学[J]. 有机化学, 2014 , 34(2) : 316 -324 . DOI: 10.6023/cjoc201307029
The two naturally occurring isotopes of lithium, 6Li and 7Li, have important roles in the nuclear energy industry. Among many techniques for the separation of lithium isotopes, high isotope separation factors are usually realized with the polydentate complex method. Crown ethers, for their selective-complexing ability with metal cations, have been regarded as perhaps the most effective extractants for lithium isotope separation. This review summarizes the application of crown ether and crown ether chelating resin for lithium isotope separation based on polydentate complexing method, exemplify recent developments in complexation of metal-containing crown ethers with metal cations, and prospect their potential in separation of lithium isotopes.
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