meso-四(4-二茂铁甲酰氧基苯基)卟啉及其锌配合物的线性与非线性光学性质
收稿日期: 2013-08-28
修回日期: 2013-09-19
网络出版日期: 2013-10-25
基金资助
国家自然科学基金（Nos.21102068，11174159）和内蒙古自治区自然科学基金（No.2013MS0207）资助项目.
Linear and Nonlinear Optical Properties of meso-Tetra(4-ferrocenylcarbonyloxyphenyl)porphyrin and Its Zinc(Ⅱ) Complex
Received date: 2013-08-28
Revised date: 2013-09-19
Online published: 2013-10-25
Supported by
Project supported by the National Natural Science Foundation of China (Nos. 21102068, 11174159) and the Natural Science Foundation of Inner Mongolia (No. 2013MS0207).
赵海英 , 顾雪松 , 鄢小卿 , 刘智波 , 陈强 , 边占喜 . meso-四(4-二茂铁甲酰氧基苯基)卟啉及其锌配合物的线性与非线性光学性质[J]. 有机化学, 2014 , 34(2) : 371 -375 . DOI: 10.6023/cjoc201308036
meso-Tetra(4-ferrocenylcarbonyloxyphenyl)porphyrin and its zinc(Ⅱ) complex were synthesized. Their linear and nonlinear optical properties were investigated using UV-Vis absorption spectra, steady state and time-resolved fluorescence spectra and open-aperture Z-scan measurements. The results indicated that the introduction of ferrocene to porphyrin had not affected the absorption spectra of porphyrin, but quenched the fluorescence intensively and shortened the fluorescence lifetimes of porphyrin, which indicated that there was almost no interaction between porphyrin and ferrocene in the ground state, but a strong interaction in the excited state. The reverse saturable absorptions of meso-tetra(4-ferrocenylcarbonyloxyphenyl)- porphyrin and its zinc(Ⅱ) complex were weaker than those of the corresponding meso-tetra(4-benzoyloxyphenyl)porphyrin and its zinc(Ⅱ) complex, but were stronger than that of fullerene C60 with excellent performance.
Key words： ferrocene; porphyrin; spectral property; Z-scan
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