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2014 , Vol. 34 >Issue 2: 278 - 291

DOI: https://doi.org/10.6023/cjoc201308031

综述与进展

Pd-NHC络合物催化交叉偶联反应的新进展

  • 倪晨 ,
  • 沈安 ,
  • 曹育才 ,
  • 叶晓峰
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  • a 上海市聚烯烃催化技术重点实验室 上海 200062;
    b 上海化工研究院 有机化工研究所 上海 200062

收稿日期: 2013-08-26

  修回日期: 2013-10-28

  网络出版日期: 2013-11-14

基金资助

上海市科学技术委员会（Nos.12NM0504500和13XD1421700）资助项目.

收起

New Progress in Crossing Coupling Reactions Catalyzed by Pd-NHC Complexes

  • Ni Chen ,
  • Shen An ,
  • Cao Yucai ,
  • Ye Xiaofeng
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  • a Shanghai Key Laboratory of Catalysis Technology for Polyolefins, Shanghai 200062;
    b Organic Chemistry Division, Shanghai Research Institute of Chemical Industry, Shanghai 200062

Received date: 2013-08-26

  Revised date: 2013-10-28

  Online published: 2013-11-14

Supported by

Project supported by the Shanghai Municipal Science and Technology Commission (Nos. 12NM0504500, 13XD1421700).

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摘要

钯催化的交叉偶联反应能非常有效且方便构建碳-碳键并应用于农药、医药、新型材料和有机中间体等领域. 多年来，各种不同结构的配体以及新型的催化体系被不断开发出来. 其中N-杂环卡宾（NHC）配体毒性低，稳定性好，同时在反应过程中具备良好的配位能力，因而被作为新一代催化体系应用于各种不同的交叉偶联反应中. 根据NHC结构特点综述了近年来新开发的Pd-NHC催化剂及其在多种交叉偶联反应中的应用.

关键词： 钯催化剂; N-杂环卡宾; 交叉偶联反应

本文引用格式

倪晨 , 沈安 , 曹育才 , 叶晓峰 . Pd-NHC络合物催化交叉偶联反应的新进展[J]. 有机化学, 2014 , 34(2) : 278 -291 . DOI: 10.6023/cjoc201308031

Abstract

Palladium-catalyzed cross-coupling reaction has become one of the most powerful and convenient protocol for the construction of carbon-carbon bonds in agrochemistry, pharmaceutical chemistry, materials and synthetic chemistry. In recent years, a variety of different structures of ligands and novel catalysts have been widely explored. Wherein N-heterocyclic carbene (NHC) ligands are employed as new generation catalysts in cross-coupling reactions due to low toxicity, good stability as well as appropriate coordination ability. The application of new developed Pd-NHC catalysts in cross-coupling reactions is reviewed according to the characteristics of NHC structures.

Key words： Pd catalyst; N-heterocyclic carbene (NHC); cross-coupling reaction

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