CsOH/DMSO促进下卤代芳烃与酚的反应：一种合成二芳基醚的简便方法
收稿日期: 2013-10-16
修回日期: 2013-11-18
网络出版日期: 2013-11-25
基金资助
国家自然科学基金（Nos. 21073132，20902070）资助项目.
CsOH/DMSO Promoted Reactions of Aryl Halides with Phenols: A Convenient Method for the Synthesis of Diaryl Ethers
Received date: 2013-10-16
Revised date: 2013-11-18
Online published: 2013-11-25
Supported by
Project supported by the National Natural Science Foundation of China (Nos. 21073132, 20902070).
陈平良 , 陆世杰 , 胡新根 , 徐清 . CsOH/DMSO促进下卤代芳烃与酚的反应：一种合成二芳基醚的简便方法[J]. 有机化学, 2014 , 34(1) : 112 -117 . DOI: 10.6023/cjoc201310021
The reactions of aryl halides with phenols promoted by CsOH/dimethyl sulfoxide (CsOH/DMSO) led to diaryl ethers. This method was free of transition metal catalysts and ligands, and could be performed without inert gas protection. Therefore, it was a concise and green synthetic method. Based on the experimental results, a mechanism involving the benzyne intermediates is supposed.
Key words： aryl halides; phenols; diaryl ethers; CsOH; dimethyl sulfoxide (DMSO); benzyne
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