含咔唑基苯并咪唑衍生物的合成
收稿日期: 2013-11-13
修回日期: 2014-01-20
网络出版日期: 2014-01-24
基金资助
广东省大学生创新（No. 1055912003）资助项目.
Syntheses of Benzoimidazole Derivatives Containing Carbazole Unit
Received date: 2013-11-13
Revised date: 2014-01-20
Online published: 2014-01-24
Supported by
Project supported by the University Student Innovative Program of Guangdong Province (No. 1055912003).
卞垒 , 曾向潮 , 何如 , 罗创龙 , 林志强 . 含咔唑基苯并咪唑衍生物的合成[J]. 有机化学, 2014 , 34(5) : 994 -998 . DOI: 10.6023/cjoc201311018
Two series of novel benzoimidazole derivatives containing carbazole unit were synthesized via condensation-cyclization of N-alkylcarbazole-3-formaldehyde with 1,2-diaminobenzene in "one pot" reaction without catalyst. The effects of temperature, selection & amount of solvents and molar ratio of the two reagents on the reactions have been investigated; significantly, one of these two series of benzoimidazole derivatives could be prepared as the major products selectively by changing the molar ratio of the two reagents.
Key words： benzoimidazole; carbazole; organic synthesis
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