新型茚基膦金配合物的合成及其在炔烃水合反应中的催化作用研究
收稿日期: 2014-01-23
修回日期: 2014-02-22
网络出版日期: 2014-03-12
基金资助
国家自然科学基金（Nos. 21072071，21272088）资助项目.
Synthetic and Structural Studies on Indenyl Phosphine Gold Complexes and Application as Catalyst for Hydration of Alkynes
Received date: 2014-01-23
Revised date: 2014-02-22
Online published: 2014-03-12
Supported by
Project supported by the National Natural Science Foundation of China (Nos. 21072071, 21272088).
韩治军 , 毛树兰 , 彭晖 , 皮云宵 , 陈友 , 刘盛华 , 余广鳌 . 新型茚基膦金配合物的合成及其在炔烃水合反应中的催化作用研究[J]. 有机化学, 2014 , 34(5) : 893 -897 . DOI: 10.6023/cjoc201401037
Four novel indenyl phosphine gold complexes were prepared by the reaction of indenyl phosphine with AuCl-(SMe)2. All products 1～4 have been fully characterized by elemental analysis, spectroscopy, and X-ray crystal diffraction techniques for 2 and 4. Complex 2 has been found efficiently to catalyze hydration of alkyne with the advantages of mild reaction conditions, less catalyst, excellent atomic economy and environmental friendly.
Key words： indenyl; phosphine; gold; alkyne; hydration reaction
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