金属离子响应型荧光传感分子的设计原理及研究进展
收稿日期: 2014-02-28
修回日期: 2014-03-18
网络出版日期: 2014-04-02
基金资助
国家自然科学基金（Nos.21064006，21161018，21262032）、甘肃省自然科学基金（No.IRT1177）及教育部长江学者和创新团队发展计划（No.1010RJZA018）资助项目.
Principle and the Research Progress of Fluorescent Chemosensors for Cations Recognition
Received date: 2014-02-28
Revised date: 2014-03-18
Online published: 2014-04-02
Supported by
Project supported by the National Natural Science Foundation of China (Nos. 21064006, 21161018, 21262032), the Program for Changjiang Scholars and Innovative Research Team in University of Ministry of Education of China (No. IRT1177) and the Natural Science Foundation of Gansu Province (No. 1010RJZA018).
荧光传感凭借其高灵敏度、可实现远程监测和实时性等优越性而广受关注，在离子识别中常被用于离子识别信号的输出. 随着主客体化学的迅速发展，许多具有良好性能的离子响应型荧光探针相继被报道，从分子内电荷转移（ICT）、光诱导的电子转移（PET）、荧光共振能量转移（FRET）、激发态分子内质子转移（ESIPT）、激基缔合物的生成/消失、螯合作用导致的荧光增强（CHEF）等不同机理对荧光传感型离子识别受体的设计思路进行了理论阐释，归纳总结了近5年来相关文献报道，阐述了其研究现状和研究进展，并展望了该领域的研究方向.
张鹏 , 张有明 , 林奇 , 姚虹 , 魏太保 . 金属离子响应型荧光传感分子的设计原理及研究进展[J]. 有机化学, 2014 , 34(7) : 1300 -1321 . DOI: 10.6023/cjoc201402037
Fluorescent chemosensors received more and more attention because these kinds of chemosensors possess a lot of advantages such as high sensitivity, realize tele-monitor and real-time detection. It was also used as signal output in ion recognition. With the rapid development of host-guest chemistry, a series of fluorescent sensors with good properties have been reported. In this review the research progress of fluorescent chemosensors in terms of recognition principle for ion recognition in resent five years was briefly reviewed based on intramolecular charge transfer (ICT), photoinduced electron transfer (PET), fluorescence resonance energy transfer (FRET), excited-state intramolecular proton transfer (ESIPT), monomer-excimer (EM) and chelation-enhanced fluorescence (CHEF), etc. The developing orientation for further research is presented.
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