β-环糊精的固载及其应用最新研究进展
收稿日期: 2014-02-19
修回日期: 2014-03-14
网络出版日期: 2014-04-10
基金资助
国家自然科学基金（No.21306176）和浙江工业大学科研启动基金（No.G2817101103）资助项目.
Recent Advances in the Immobilization of β-Cyclodextrin and Their Application
Received date: 2014-02-19
Revised date: 2014-03-14
Online published: 2014-04-10
Supported by
Project supported by the National Natural Science Foundation of China (No.21306176) and the Scientific Research Launching Foundation of Zhejiang University of Technology (No.G2817101103).
环糊精由于其优异的结构特征和物理化学性质，已成为构筑各种功能材料的优良结构单元.本综述以β-环糊精的共价固载为主，详细综述了目前β-环糊精的固载及其应用最新研究进展，主要包括固载化β-环糊精在环境污染物吸附、药物分子的负载和缓释、分析检测、手性分离、催化、织物整理和表面功能化等领域的应用.上述各部分，根据载体或应用方式的不同，系统介绍了β-环糊精的固载及固载化β-环糊精的性能.指出固载化β-环糊精在催化和表面功能化领域的应用虽然目前还处于起步阶段，却极具研究价值，对固载化β-环糊精进一步的功能化是今后基于β-环糊精构筑超分子仿生催化体系的主要研究方向.
沈海民 , 纪红兵 , 武宏科 , 史鸿鑫 . β-环糊精的固载及其应用最新研究进展[J]. 有机化学, 2014 , 34(8) : 1549 -1572 . DOI: 10.6023/cjoc201402024
Cyclodextrin has become an excellent unit in the construction of various functional materials due to its unique structural characteristics and physical-chemical properties.Herein, the immobilization of β-cyclodextrin and their application at present have been reviewed in detail focusing on the covalent immobilization, especially including the application of the immobilized β-cyclodextrin in the environmental pollutants adsorption, drug loading and releasing, analysis and detection, chiral separation, catalysis, textile finishing, surface functionalization and so on.In the application mentioned above, the immobilization of β-cyclodextrin and their performance were presented systematically according to the supporter or application modes.It is pointed out that the applications of the immobilized β-cyclodextrin in catalysis and surface functionalization are just in their infancy, but having promising prospect.The further functionalization of the immobilized β-cyclodextrin will be the focus in the construction of supramolecular biomimetic catalytic systems based on β-cyclodextrin in future.
Key words： β-cyclodextrin; immobilization; application; advances
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