一锅法合成基于丁二炔-苯环冠醚的[2]轮烷
收稿日期: 2014-06-07
修回日期: 2014-07-19
网络出版日期: 2014-08-11
基金资助
国家自然科学基金(No.21072066)和广东省省部产学研基金(No.2012B090700003)资助项目.
One-Pot Synthesis of A New [2]rotaxane Based on the Phenylene-Diacetylene Crown Ether
Received date: 2014-06-07
Revised date: 2014-07-19
Online published: 2014-08-11
Supported by
Project supported by the National Natural Science Foundation of China (No. 21072066) and the Key Project on the Integration of Industry, Education and Research of Guangdong Province (No. 2012B090700003).
陈木娟 , 郭浩玉 , 周松根 , 陈坤 , 蒋腊生 . 一锅法合成基于丁二炔-苯环冠醚的[2]轮烷[J]. 有机化学, 2014 , 34(12) : 2559 -2565 . DOI: 10.6023/cjoc201406009
A new [2]rotaxane was synthesized via one-pot method, based on the assembly of the phenylene-diacetylene crown ether (acted as ring molecule) and the paraquat derivative (acted as semi-axle molecule). The HR-MS, 1H NMR and 13C NMR spectra have confirmed that one phenylene-diacetylene crown ether ring threaded though the axle molecule forming the corresponding [2]rotaxane, and the macrocyclic ring moves from one 4,4'-bipyridinium station to another 4,4'-bipyridinium station.
Key words： phenylene-diacetylene crown ether; one-pot method; synthesis; [2]rotaxane
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