苯炔对双键插入反应的研究进展
收稿日期: 2014-11-26
修回日期: 2014-12-15
网络出版日期: 2015-01-09
基金资助
国家自然科学基金(No. 21002021)和河南省高校科技创新人才支持计划基金(No. 13HASTIT010)资助项目.
Recent Advances in Aryne Double Bond Insertion
Received date: 2014-11-26
Revised date: 2014-12-15
Online published: 2015-01-09
Supported by
Project supported by National Natural Science Foundation of China (No. 21002021) and the Program for Science & Technology Innovation Talents in Universities of Henan Province (No. 13HASTIT010).
吴春蕊 , 杨玉坡 , 史峰 . 苯炔对双键插入反应的研究进展[J]. 有机化学, 2015 , 35(4) : 770 -780 . DOI: 10.6023/cjoc201411041
Aryne double bond insertion generates an ortho-quinomethide-typed intermediate, which, like aryne itself, is one of the most important reactive intermediates in organic reactions. This review summarizes recent advances in this field and the potential applications in synthetic organic chemistry, with a focus on the reaction mechanism, as well as the structure and reactivity of the ortho-quinomethide intermediates.
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