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2015 , Vol. 35 >Issue 6: 1270 - 1275

DOI: https://doi.org/10.6023/cjoc201412021

研究论文

碳负载铜一锅法催化合成苯并硒唑类衍生物

  • 周美云 ,
  • 吴照钧 ,
  • 李毅群 ,
  • 郑文杰 ,
  • 纪盛滨 ,
  • 周华
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  • a 暨南大学化学系 广州 510632;
    b 暨南大学理工学院食品科学与工程系 广州 510632

收稿日期: 2014-12-12

  修回日期: 2015-01-20

  网络出版日期: 2015-02-10

基金资助

国家自然科学基金(Nos. 31101323, 31000816)资助项目.

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One-Pot Synthesis of Benzo[d][1,3]selenazole Derivatives by Using Carbon-Supported Copper Catalyst

  • Zhou Meiyun ,
  • Wu Zhaojun ,
  • Li Yiqun ,
  • Zheng Wenjie ,
  • Ji Shengbin ,
  • Zhou Hua
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  • a Department of Chemistry, Jinan University, Guangzhou 510632;
    b Department of Food Science and Engineering, Jinan University, Guangzhou 510632

Received date: 2014-12-12

  Revised date: 2015-01-20

  Online published: 2015-02-10

Supported by

Project supported by the National Natural Science Foundation of China (Nos. 31101323, 31000816).

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摘要

建立了一种简单实用、经济高效的以邻溴苯胺为起始原料, 廉价的活性碳负载铜为催化剂, 在室温条件下一锅法合成苯并硒唑类衍生物的方法, 得到了中等到优良的产率. 本方法具有催化剂廉价易得、操作简便、合成效率高的优点.

关键词： 一锅法合成; 苯并硒唑; 碳负载铜催化

本文引用格式

周美云 , 吴照钧 , 李毅群 , 郑文杰 , 纪盛滨 , 周华 . 碳负载铜一锅法催化合成苯并硒唑类衍生物[J]. 有机化学, 2015 , 35(6) : 1270 -1275 . DOI: 10.6023/cjoc201412021

Abstract

A simple, efficient, inexpensive one-pot method for the benzo[d][1,3]selenazole derivatives synthesized from 2-bromoaniline was developed by using cheap carbon-supported copper as catalyst at room temperature. The reaction provides an efficient protocol to a series of benzo[d][1,3]selenazole derivatives in good to high yields, and benefits of readily available catalyst and synthesis of high efficiency.

Key words： one-pot synthesis; benzo[d][1,3]selenazole; carbon-supported copper

参考文献

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