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2015 , Vol. 35 >Issue 5: 937 - 946

DOI: https://doi.org/10.6023/cjoc201501004

研究专题

芳基高价碘盐诱导的亲电环化反应研究

  • 陈静 ,
  • 曲红梅 ,
  • 彭静 ,
  • 陈超
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  • a 天津大学化工学院 系统生物工程教育部重点实验室 天津市生物制药工程重点实验室 天津 300072;
    b 清华大学化学系 生命有机磷化学及化学生物学教育部重点实验室 北京 100084

收稿日期: 2015-01-05

  修回日期: 2015-01-30

  网络出版日期: 2015-02-10

基金资助

国家自然科学基金(Nos.21102099,21102080,21372138)和教育部-清华大学自主科研计划(No.2011Z02150)资助项目.

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Study of Electrophilic Cyclization Reactions Triggered by Diaryliodonium Salts

  • Chen Jing ,
  • Qu Hongmei ,
  • Peng Jing ,
  • Chen Chao
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  • a Key Laboratory of Systems Bioengineering, Ministry of Education, Tianjin Key Laboratory of Biological and Pharma- ceutical Engineering, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072;
    b Key Laboratory of Bioorganic Phosphorus Chemistry & Chemical Biology, Ministry of Education, Department of Chemistry, Tsinghua University, Beijing 100084

Received date: 2015-01-05

  Revised date: 2015-01-30

  Online published: 2015-02-10

Supported by

Project supported by the National Natural Science Foundation of China (Nos.21102099, 21102080, 21372138) and the Tsinghua University Initiative Scientific Research Program (No.2011Z02150).

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摘要

亲电试剂诱导的环化反应是构建环状化合物的有效策略, 而利用芳基高价碘盐作为亲电试剂诱导环化反应已经取得了诸多研究进展. 在这些亲电环化反应中, 高价碘盐不仅可以作为芳基化试剂诱导环化反应形成芳基取代环化物, 还可以诱导苯并环化反应, 形成苯并环状化合物.

关键词： 芳基高价碘; 亲电环化; 芳化-环化反应; 苯并环化反应

本文引用格式

陈静 , 曲红梅 , 彭静 , 陈超 . 芳基高价碘盐诱导的亲电环化反应研究[J]. 有机化学, 2015 , 35(5) : 937 -946 . DOI: 10.6023/cjoc201501004

Abstract

Electrophilic cyclization reactions are one of the most useful strategies for the construction of various cyclic compounds and significant progress has been made in the electrophilic cyclizations triggered by diaryliodonium salts. In these new types of electrophilic cyclization reactions, diaryliodonium salts can not only act as arylation reagents to initiate arylation-cyclization reactions giving aryl-substituted compounds, but also to be involved in the benzocyclization to give benzocycles.

Key words： diaryliodonium salts; electrophilic cyclization; arylation-cyclization reactions; benzocyclization

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