纳米钯催化的高效Suzuki偶联反应
收稿日期: 2015-02-14
修回日期: 2015-06-04
网络出版日期: 2015-06-12
基金资助
山西省自然科学基金(No. 2012021007-2)资助项目.
Nanoparticles Pd-Catalyzed Highly Efficient Suzuki Cross-Coupling Reaction
Received date: 2015-02-14
Revised date: 2015-06-04
Online published: 2015-06-12
Supported by
Project supported by the Natural Science Foundation of Shanxi Province (No. 2012021007-2).
赵晓霞 , 常宏宏 , 李兴 , 魏文珑 . 纳米钯催化的高效Suzuki偶联反应[J]. 有机化学, 2015 , 35(8) : 1650 -1656 . DOI: 10.6023/cjoc201502022
An efficient protocol for the Suzuki reactions catalyzed by Pd(PPh3)4-derived nanoparticles palladium catalyst has been developed. This method is able to prepare a variety of biaryls under air atmosphere at 25~90 ℃ in DMF/H2O mixture solvent. In the presence of this catalyst, the cross-coupling reactions of aryl halides with arylboronic acids proceed smoothly and afforded the desired coupling products with high yields. The catalyst could be recycled 6 times without loss of activity and decrease of yield.
Key words： nanoparticles palladium; Suzuki reaction; Pd/Al2O3; biphenyls; H2O
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