银催化炔丙醇与芳基异腈交叉偶联反应:原子经济性合成N-芳基-2,3-联烯酰胺
收稿日期: 2015-05-19
修回日期: 2015-06-15
网络出版日期: 2015-06-24
基金资助
国家自然科学基金(Nos. 31101010, 21202016和21372038)资助项目.
Silver-Catalyzed Cross-Coupling Reaction of Propargylic Alcohols and Arylisocyanides: An Atom-Economic Synthesis of N-Aryl-2,3-allenamides
Received date: 2015-05-19
Revised date: 2015-06-15
Online published: 2015-06-24
Supported by
Project supported by the National Natural Science Foundation of China (Nos. 31101010, 21202016 and 21372038).
徐文帅 , 赵寿经 , 骆晓沛 , 宋金娜 , 刘建全 , 毕锡和 , 廖沛球 . 银催化炔丙醇与芳基异腈交叉偶联反应:原子经济性合成N-芳基-2,3-联烯酰胺[J]. 有机化学, 2015 , 35(10) : 2095 -2101 . DOI: 10.6023/cjoc201505025
A silver-catalyzed cross-coupling of propargylic alcohols and aryl isocyanides to N-aryl-2,3-allenamides has been developed. This reaction is both atom and step economic and applicable to a broad scope of substrates, affording a range of synthetically useful N-aryl-2,3-allenamides in good to high yields under mild conditions. This protocol has successfully solved the problem in our previous report that the isocyanides were limited to active methylene isocyanides, provided an extremely simple way to access the synthetically useful N-aryl-2,3-allenamides.
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