低价(正一价)镁金属化合物的合成及其应用研究进展
收稿日期: 2015-07-16
修回日期: 2015-09-12
网络出版日期: 2015-09-17
基金资助
国家自然科学基金(No. 21372117)、江苏省自然科学基金(Nos. BK20141468, BK20130952)和江苏省“青蓝工程”资助项目.
Synthesis of Magnesium(I) Complexes and Their Applications
Received date: 2015-07-16
Revised date: 2015-09-12
Online published: 2015-09-17
Supported by
Project supported by the National Natural Science Foundation of China (No. 21372117), the Natural Science Foundation of Jiangsu Province (Nos. BK20141468, BK20130952) and the Qing Lan Project of Jiangsu Province.
马猛涛 , 王未凡 , 姚薇薇 . 低价(正一价)镁金属化合物的合成及其应用研究进展[J]. 有机化学, 2016 , 36(1) : 72 -82 . DOI: 10.6023/cjoc201507015
The valence of the alkaline-earth metals (group 2 metals) usually is 0 and +2. In 2007, the first room temperature stable magnesium(I) complexes were synthesized. Subsequently a series of different organic ligands stablized Mg(I) complexes have been prepared. They can be used as hydrocarbon soluble, stoichiometric, selective, and safe reducing agents in organic and inorganic reactions to replace some traditional reductants. In this review the synthesis of room temperature stable magnesium(I) complexes and their applications in organic and inorganic chemistry are briefly introduced.
Key words： metal-metal bond; univalence; magnesium; synthesis; applications
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