磁性纳米粒子负载亚胺吡啶钯催化Suzuki反应研究
收稿日期: 2015-07-16
修回日期: 2015-09-22
网络出版日期: 2015-09-30
基金资助
江苏省自然科学基金(No. BK20150282)和苏州科技学院科研基金(No. XKQ201417)资助项目.
Magnetic Nanoparticle Supported Imino-pyridine Palladium Catalyzed Suzuki Reactions
Received date: 2015-07-16
Revised date: 2015-09-22
Online published: 2015-09-30
Supported by
Project supported by the Natural Science Foundation of Jiangsu Province (No. BK20150282) and the Scientific Research Foundation of Suzhou University of Science and Technology (No. XKQ201417).
张强 , 李继航 , 赵鑫 . 磁性纳米粒子负载亚胺吡啶钯催化Suzuki反应研究[J]. 有机化学, 2016 , 36(1) : 130 -136 . DOI: 10.6023/cjoc201507013
A new magnetic nanoparticle supported palladium catalyst was successfully prepared by attaching palladium acetates to imino-pyridine ligand functionalized silica-coated nano-Fe3O4. The as-prepared catalyst was characterized by element analysis, FTIR, TEM, XPS and ICP-AES. It was found to be an efficient catalyst for Suzuki reactions in aqueous medium. And the reactions of various aryl bromides with arylboronic acids could be carried out under air and low Pd loading conditions with 83%～98% yields. Moreover, the catalyst could be easily recovered by magnetic separation and reused five times without a significant loss of catalytic activity.
Key words： magnetic nanoparticle; palladium catalyst; Suzuki reaction; Schiff base
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