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2016 , Vol. 36 >Issue 2: 412 - 416

DOI: https://doi.org/10.6023/cjoc201509039

研究简报

含有仲氨基团的甲基丙烯酸酯单体的原子转移自由基聚合研究

  • 简祖凯 ,
  • 杨阳 ,
  • 郎美东 ,
  • 李永军
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  • a 华东理工大学材料科学与工程学院 超细材料制备与应用教育部重点实验室 上海 200237;
    b 中国科学院上海有机化学研究所 上海 200032

收稿日期: 2015-09-19

  修回日期: 2015-10-16

  网络出版日期: 2015-10-26

基金资助

国家自然科学基金(No. 21204098)资助项目

收起

Atom Transfer Radical Polymerization of Secondary Amine Containing Methacrylate Monomer

  • Jian Zukai ,
  • Yang Yang ,
  • Lang Meidong ,
  • Li Yongjun
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  • a Key Laboratory for Ultrafine Materials of Ministry of Education, School of Materials Science and Engineering, East China University of Science and Technology, Shanghai 200237;
    b Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032

Received date: 2015-09-19

  Revised date: 2015-10-16

  Online published: 2015-10-26

Supported by

Project supported by the National Natural Science Foundation of China (No. 21204098)

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摘要

聚(4-甲基丙烯酰氧基-2,2,6,6-四甲基哌啶氮氧自由基)(PTMA)是一种具有应用前景的锂离子电池正极材料, 一般通过2,2,6,6-四甲基哌啶醇-4-甲基丙烯酸酯(TMPM)的自由基聚合及进一步氧化来制备. 但是TMPM的可控自由基聚合受制于其分子中的仲氨基团. 通过对不同的引发剂和催化体系TMPM的原子转移自由基聚合(ATRP)进行了研究, 得到了TMPM最优的ATRP聚合条件, 为合成具有不同分子量或拓扑结构的自由基聚合物奠定了基础.

关键词： 甲基丙烯酸酯; 仲氨; 原子转移自由基聚合

本文引用格式

简祖凯 , 杨阳 , 郎美东 , 李永军 . 含有仲氨基团的甲基丙烯酸酯单体的原子转移自由基聚合研究[J]. 有机化学, 2016 , 36(2) : 412 -416 . DOI: 10.6023/cjoc201509039

Abstract

Radical polymer poly(2,2,6,6-tetramethylpiperidinyloxy-4-yl methacrylate) (PTMA), a potential cathode materials, was prepared by radical polymerization of 2,2,6,6-tetramethylpiperidin-4-yl methacrylate (TMPM) containing secondary amine group, followed by oxidation into radical polymer. However, the living radical polymerization of TMPM was hindered by its secondary amine group. The optimized atom transfer radical polymerization condition for TMPM via screening various initiators and catalyst systems was reported, and poly(2,2,6,6-tetramethylpiperidin-4-yl methacrylate)s with different molecular weight were prepared.

Key words： methacrylate; secondary amine; atom transfer radical polymerization

参考文献

[1] Arico, A. S.; Bruce, P.; Scrosati, B.; Tarascon, J. M.; Van Schalkwijk, W. Nat. Mater. 2005, 4, 366.
[2] Bruce, P. G.; Scrosati, B.; Tarascon, J. M. Angew. Chem., Int. Ed. 2008, 47, 2930.
[3] Aricò, A. S.; Bruce, P.; Scrosati, B.; Tarascon, J. M.; Van Schalkwijk, W. Nat. Mater. 2005, 4, 366.
[4] Poizot, P.; Dolhem, F. Energy Environ. Sci. 2011, 4, 2003.
[5] Liang, Y.; Tao, Z.; Chen, J. Adv. Energy Mater. 2012, 2, 742.
[6] Nakahara, K.; Iwasa, S.; Satoh, M.; Morika, Y.; Iriyama, J.; Suguro, M.; Hasegawa, E. Chem. Phys. Lett. 2002, 359, 351.
[7] Zhao, R. R.; Zhu, L. M.; Yang, H. X. Prog. Chem. 2011, 23, 302 (in Chinese). (赵瑞瑞, 朱利敏, 杨汉西, 化学进展, 2011, 23, 302.)
[8] Deng, L. F.; Li, X. H.; Xiao, L. X.; Zhang, Y. H. Acta Polym. Sin. 2004, (1), 8 (in Chinese). (邓凌峰, 李新海, 肖立新, 张云河, 高分子学报, 2004, (1), 8.)
[9] Guo, W.; Yin, Y. X.; Xin, S.; Guo, Y. G.; Wan, L. J. Energy Environ. Sci. 2012, 5, 5221.
[10] Rostro, L.; Baradwaj, A. G..; MuLLer, A. R. MRS Commun. 2015, 5, 257.
[11] Bertrand, O.; Ernould, B.; Boujioui, F.; Vlad, A.; Gohy, J. F. Polym. Chem. 2015, 6, 6067.
[12] Sukegawa, T.; Masuko, I.; Oyaizu, K.; Nishide, H. Macromolecules 2014, 47, 8611.
[13] Janoschka, T.; Teichler, A.; Krieg, A.; Hager, M. D.; Schubert, U. S. J. Polym. Sci., Part A: Polym. Chem. 2012, 50, 1394.
[14] Wang, Y. H.; Hung, M. K.; Lin, C. H.; Lin, H. C.; Lee, J. T. Chem. Commun. 2011, 47, 1249.
[15] Hauffman, G.; Rolland, J.; Bourgeois, J. P.; Vlad, A.; Gohy, J. F. J. Polym. Sci., Part A: Polym. Chem. 2013, 51, 101.
[16] Kurosaki, T.; Lee, K. W.; Okawara, M. J. Polym. Sci., Part A: Polym. Chem. 1972, 10, 3295.
[17] Matyjaszewski, K.; Xia, J. Chem. Rev. 2001, 101, 2921.
[18] Pintauer, T.; Matyjaszewski, K. Coord. Chem. Rev. 2005, 249, 1155.
[19] Zhang, X. H.; Li, H. Q.; Li, L. T.; Lu, G. L.; Zhang, S.; Gu. L. N.; Xia, Y. Y.; Huang, X. Y. Polymer 2008, 49, 3393.

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